氯代二异丙基膦的西蒙斯氟化

Simons Process of Diisopropylchlorophosphane

通过合成新型锂离子二次电池电解质全氟二异丙基膦酸锂,研究了氯代二异丙基膦的西蒙斯氟化过程中电流和电压随时间的变化,认为有机物西蒙斯氟化过程既和阳极膜有效面积有关又和无水氟化氢中有机物的浓度有关.

The relationships of the time vs. the current and the time vs. the voltage were studied in the synthesis of lithium his （ heptafluoroisopropyl ） tetrafluorophosphate Li[（C2F7）2PF4] by Simons process from diisopropylchlorophosphane in this paper. It was received that the main controlling condition included active anodic area and the concentration of the organism in the HF.