高氮含能化合物的合成及反应性

Review on Synthesis of High-nitrogen Energetic Compounds

综述了四嗪、高氮呋咱和三(四)唑等三类高氮含能化合物(HNECs)的研究现状,叙述了它们的合成方法,介绍了几个典型HNECs的合成路线,提出了合成部分新的HNECs的研究思路。

High-nitrogen energetic compounds （HNECs） including tetrazines, high-nitrogen furazas and trizoles （or tetrazoles） have characteristics as higher positive heat of formation, better oxygen balance, higher density, and lower sensitivity. The usual synthesis methods of HNECs, and the synthesis route for typical HNECs,including BT, DAAzF and BHT are reviewed. And then some ideas to synthesize new HNECs from non-symmetrical molecular design direction are suggested, i.e. interlinkage between the tetrazine and the farazan, the tetrazine, the pyrazole.