期刊文献+

联萘酚胺的合成及拆分研究 被引量:3

下载PDF
导出
摘要 联萘酚胺是一种重要的手性配体,广泛应用于手性不对称有机合成中。本研究以2-萘酚、2-萘胺为原料,CuCl_2为催化剂,进行偶联反应,生成联萘酚胺,收率65%。再用 R-樟脑磺酸对产品进行手性拆分,分别得到 R-联萘酚胺和 S-联萘酚胺。
作者 杨会来
出处 《杭州化工》 CAS 2006年第4期12-14,共3页 Hangzhou Chemical Industry
  • 相关文献

参考文献12

  • 1Noyori Ryoji, Kitamura Masato. Enantioselective addition of organometallie reagents to earbonyl compounds: transfer, duplication and intesification of chirality [ J ]. Angewandte Chemie, 1991, 103(1):34-55.
  • 2Martin Smrcina, Miroslav Lorene, Vladimir Hanus, et. al. Synthesis of enantiornerieally pure 2,2' - dihydroxy - 1,1' - binaphthyl,2,2' - diamino - 1,1' - binaphthyl, and 2 - amino- 2' - hydroxy - 1,1' - binaphthyl. Comparison of processes operating as diastereoselective crystallization and as second order asymmetric transformation[ J ], J. Org. Chem,, 1992,57:1917- 1920.
  • 3Stepan Vyskocil,Stanislav Jaracz,Martin Smrcina,et. al. Synthesis of N- Alkylated and N- Arylated Derivatives of 2 -Amino-2' - hydroxy- 1,1' - binaphthyl (NOBIN) and 2,2' -Diamino- 1,1' -binaphthyl and Their Application in the Enantioselective Addition of Diethylzinc to Aromatic Aldehydes[J ]. J. Org. Chem., 1998,63: 7727 - 7737.
  • 4Erik M. Carreira, Robert A. Singer,Wheeseong Lee. Catalytic,Enantioselective Aldol Additions with Methyl and Ethyl Acetate O-Silyl Enolates:A Chiral Tridentate Chelate as a Ligand for Titanium(IV) [J]. J. Am. Chem. Soc., 1994, 116:8837 -8838.
  • 5Erik M,, Carreira,Wheeseong Lee, Robert A. Singer, Catalytic,Enantioselective Acetione Aldol Additions with 2 - Methoxypropene[J]. J. Am.Chem, Soc, ,1995,117:3649- 3650.
  • 6Knolker H, K,, Hermann H,, et, al. Transition Metal - Diene Complexes in Organic Synthesis, Part 28. Asymmetric catalysis in the complexation of prochiral dienes by the tricarbonyliron fragment :a novel methodology for the enantioselective synthesis of planar chiral trcarbonyl(diene) iron complexes[J]. Angew.China, Int. Ed. Engl. ,1996,3(35):341-344.
  • 7Singer R A. ,Brock J R., Carreira E M. Synthesis of a tridenrate ligand for use in TiIV- catalyzed acetate aldol addition reactions[J]. Hdvetica Chimica Acta,2003,86(4) : 1040 - 1044.
  • 8Zhang Xumu. Preparation of chiral 2 - amino- 2 - dlpheny -phosphino- 1,1' - binaphthyl derivatives as metal catalyst ligands[P]. WO 2001000581,2001 - 01 - 04.
  • 9Ding Kuiling, Xu Qiguo, Wang Yang, et al. Novd two - phase oxidative cress - coupling of the two - component molecular crystal of 2 - naphthol and 2 - naphthylamine [J]. Chemical Communications (Cambridge), 1997,7:693 - 694.
  • 10Korber K. ,Tang Wenjun, Hu Xinquan,et al.A practical synthesis of 2 - amino - 2' - hydroxy - 1, 1 ' - binaphthyl(NOBIN) [ J ]. Tetrahedron Letters, 2002,43 (40) : 7163 -7165.

同被引文献65

引证文献3

二级引证文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部