期刊文献+

溶胶-凝胶法合成纳米TiO_2粉体的研究进展 被引量:9

Advances of Preparation for Nanometer TiO_2 Powder by Sol-gel Method
下载PDF
导出
摘要 概述了利用溶胶-凝胶法合成纯纳米Ti O2粉体时不同合成条件对制备结果的影响;综述了利用溶胶-凝胶法合成金属及非金属离子掺杂Ti O2粉体、半导体复合纳米Ti O2、贵金属沉积以及固体超强酸化纳米Ti O2的研究现状,并指出不同方法提高光催化活性的机理在于促进电子-空穴的分离或改变能带及表面结构。针对制备纳米Ti O2粉体中存在的问题,指出未来的研究方向应是提高Ti O2催化活性的机理研究、可见光化纳米Ti O2的制备以及工业化生产条件探索等。 The influence of synthesis condition on pure nano-TiO2 powder is reviewed. The advances in synthesis of ion-doped TiO2 powder, coupled semiconductor powder, rare metal deposited TiO2 powder and solid super acid TiO2 by sol gel method are summarized. The mechanisms for the enhancement of the photocatalytic activity of the modified nano-TiO2 are introduced and enhancement mechanism lies in the separation of electron-hole pairs or the variation of electronic band structure or surface state. As to the problems in preparation of nanometer TiO2, further study should be focused on the mechanism for the enhancement of the photocatalytic activity of TiO2, the preparation of nanometer TiO2 with visible light activity and the study of conditions for industrial production.
出处 《材料导报》 EI CAS CSCD 北大核心 2006年第F11期64-67,共4页 Materials Reports
基金 国家自然科学基金项目(20276015) 河北省自然科学基金项目(203364)
关键词 溶胶-凝胶法 纳米TIO2 离子掺杂 半导体复合 贵金属沉积 固体超强酸 sol-gel method, nanometer TiO2, ion doping, coupled semiconductor, rare metal depositing, solid super acid
  • 相关文献

参考文献32

  • 1Keshmiri M,Mohseni M,Troczynski T.Development of novel TiO2 sol-gel-derived composite and its photocatalytic activities for trichloroethylene oxidation[J].Appl Cataly B:Env,2004,53(4):209
  • 2Mao L Q,Li Q L,Dang H X,et al.Synthesis of nanocrystalline TiO2 with high photoactivity and large specific surface area by sol-gel method[J].Mater Res Bull,2005,40(2):201
  • 3程小苏,曾令可,黄浪欢,王慧.TiO_2光催化剂的制备过程与配方优化[J].华南理工大学学报(自然科学版),2003,31(2):14-18. 被引量:18
  • 4卫芝贤,逯宝娣,王超.胶凝方式对制备纳米二氧化钛的影响[J].稀有金属,2002,26(1):28-31. 被引量:5
  • 5张春光,邵磊,沈志刚,陈建峰,周月.中和水解法制备纳米TiO_2的研究[J].化工进展,2003,22(1):53-55. 被引量:37
  • 6Stefchev P,Blaskov V,Machkov M,et al.Synthesis and characterization of high dispersed TiO2[J].Inorg Mater,2001,(3):531
  • 7Su C,Hong B Y,Tseng C M.Sol-gel preparation and photocatalysis of titanium dioxide[J].Catalysis Today,2004,96(3):119
  • 8陈龙武,甘礼华.气凝胶[J].化学通报,1997(8):21-27. 被引量:80
  • 9沈伟韧,贺飞,赵文宽,方佑龄.超临界干燥法制备TiO_2气凝胶[J].催化学报,1999,20(3):365-367. 被引量:22
  • 10Kolenko Y V,Garshev A V,Churagulov B R.Photocatalytic activity of sol-gel derived titania converted into nanocrystalline powders by supercritical drying[J].Photochem Photobio A:Chem,2005,172(1):19

二级参考文献116

共引文献486

同被引文献173

引证文献9

二级引证文献43

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部