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Ni-YSZ阳极支撑SOFC阴极LSM-YSZ的LSM同源离子渗透改性 被引量:1

LSM-YSZ Cathode of Ni-YSZ Anode Supported SOFC Modified by Homogeneity Ion of LSM Infiltration
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摘要 通过丝网印刷的方法在市场可获得的YSZ/NiO-YSZ半电池上印刷LSM-YSZ浆料,烧结后构成Ni-YSZ阳极支撑的SOFC试验电池。通过溶液渗透的方法,研究了La(NO3)3和La(NO3)3-Mn(NO3)2复合渗透电池性能的影响。以水分含量3%的纯氢气为燃料,未渗透电池800℃的峰值功率为0.202 W.cm-2,La(NO3)3溶液渗透后电池800℃的峰值功率为0.428 W.cm-2;在渗透La(NO3)3后的电池上再用Mn(NO3)2复合渗透,电池800℃的峰值功率为0.92 W.cm-2,电池在800℃保持38 h,峰值功率可以保持在0.46 W.cm-2。 LSM-YSZ slurry was screen-printed on commercial available green pellet and was sintered to form anode supported SOFC. Effects of La(NO3)3 infiltration and La(NO3)3-Mn(NO3)2 co-infdtration were studied. The cell was fueled by pure hydrogen with 3% H2O content. Peak power density at 800℃ respectively,original cell w88 0. 202 W·cm^-2, La(NO3)3 solution infdtrated cell was 0. 428 W·cm^-2, La(NO3)3-Mn (NO3)2 co-lnfiltrated cell was 0.92 W·cm^-2. Stability of co-infdtrated cell was tested, and 0.46 W·cm^-2 peak power density of co-infiltrated cell was reserved after the cell kept at 800℃ for 38 h.
出处 《稀有金属》 EI CAS CSCD 北大核心 2006年第6期761-765,共5页 Chinese Journal of Rare Metals
关键词 SOFC LSM-YSZ阴极 渗透方法 峰值功率 SOFC LSM-YSZ cathode infiltration method peak power density
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参考文献20

  • 1Nomura Hiroshi,Parekh Sandeep,Robert Selman J,et al.Fabrication of YSZ electrolyte for intermediate temperature solid oxide fuel cell using electrostatic spray deposition:Ⅰ-a comprehensive parametric study[J].Journal of Applied Electrochemistry,2005,35:61.
  • 2Nomura Hiroshi,Parekh Sandeep,Robert Selman J,et al.Fabrication of YSZ electrolyte for intermediate temperature solid oxide fuel cell using electrostatic spray deposition:Ⅱ-Cell performance[J].Journal of AppliedElectrochemistry,2005,35:1121.
  • 3Negishi H,Yamaji K,Saka N,et al.Electrophoretic depositionof YSZ powders for solid oxide fuel cells[J].Journal of Materials Science,2004,39:833.
  • 4Jung Hwa Young,Hong Kug-Sun,Kim Hyoungchul,et al.Characterization of thin-film YSZ deposited via EP-PVD technique in anode-supported OSFCs[J].Journal of the Electrochemical Society,2006,153(5):A961.
  • 5Laukaitis G,Dudonis J,Milcius D.YSZ thin films deposited bye-beam technique[J].Thin Solid Films,2006,515:678.
  • 6Kenji Kikuchi,TakujiOkaya,Wataru Hirose,et al.Fabrication of YSZ thin films by chemical vapor infiltration using NiO as oxygen source[J].Journal of the Electrochemistry Society,2003,150(10):C688.
  • 7Steele Brain C H,Heinzel Angelika.Materials for fuel-cell technologies[J].Nature,2001,414(15):345.
  • 8Zhang Xinge,Ohara Satoshi,Maric Radenka,et al.Ni-SDC cermet anode for medium-temperature solid oxide fuel cell with lanthanum gallate electrolyte[J].Journal of Power Sources,1999,83:170.
  • 9Wang Fengyun,Wan Benzu,Cheng Soofin.Study on Gd^3+ and Sm^3+ co-doped ceria * based electrolytes[J].J.Solid State Electrochemistry,2005,9:168.
  • 10Ai Na,Lu Zhe,Cheo Kongfa,et al.Low temperature solid oxide fuel cells based on Sm0.2Ce0.8O1.9 films fabricated by slurry spin coating[J].Journal of Power Sources,2006,159:637.

二级参考文献28

  • 1Eguchi K, Setoguchi T, Inoue T, et al.Electrical-properties of ceria-based oxides and their application to solid oxide fuel-cells [J]. Solid State Ionics, 1992, 52(1-3): 165.
  • 2Hibino T, Hashimoto A, Yano M, et al.High performance anodes for SOFCs operating in methane-air mixture at reduced temperatures [J]. J. Electrochem. Soc., 2002, 149(2): A133.
  • 3Xia C R, Liu M L.Low-temperature SOFCs based on Gd0.1Ce0.9O1.95 fabricated by dry pressing [J]. Solid State Ionics, 2001, 144 (3-4): 249.
  • 4Xia C R, Liu M L.A simple and cost-effective approach to fabrication of dense ceramic membranes on porous substrates [J]. J.Am.Ceram. Soc., 2001, 84(8): 1903.
  • 5Peng R R, Xia C R, Liu X Q, et al.Intermediate-temperature SOFCs with thin Ce0.8Y0.2O1.9 films prepared by screen-printing [J]. Solid State Ionics, 2002, 152-153: 561.
  • 6Steele B C H.Appraisal of Ce1-yGdyO2-y/2 electrolytes for IT-SOFC operation at 500 ℃ [J]. Solid State Ionics, 2000, 129 (1-4): 95.
  • 7Yin Y H, Zhu W, Xia C R, et al.Gel-cast NiO-SDC composites as anodes for solid oxide fuel cells [J]. J. Power Sources, 2004, 4(5): A52.
  • 8Teraoka Y, Zhang H M, Yamazoe N. Mixed ionic-electronic conductivity d La1-xSrxCo1-yFeyO3-δ perovskite-type oxides [J]. Mater. Res. Bull., 1988, 23(1): 51.
  • 9Mizusaki J, Tabuchi J, Matsuura T, et al. Electrical conductivity and Seebeck coefficient of nonstiochiometric La1-xSrxCoO3-δ[J]. J.Electrochem. Soc., 1989, 136: 2082.
  • 10Tsai C Y, Dixon A G, Ma Y H, et al. Dens perovskite, La1-x A',Fe1-yCorO3-δ(A'= Ba, Sr, Ca), membrane synthesis, applicathins, and characterization [J]. J. Am. Ceram. Soc., 1998, 81(6):1437.

共引文献11

同被引文献17

  • 1Ye Siyu,Vijh Ashok K.Non-noble metal-carbonized aerogel composites as electrocatalysis for the oxygen reduction reaction[J].Electrochemistry Communication,2003,5:272.
  • 2Subramanian Nalini P,Kumaraguru Swaminatha P,Colo-Mercado Hector,Kim Hansung,Popov Branko N,Black Timothy,Chen Donna A.Studies on Co-based catalysts supported on modified carbon substrates for PEMFC cathodes[J].Journal of Power Sources,2006,57:56.
  • 3Alvim Ferraz M C M,Gaspar C M T B.Active carbons impregnated before activation of olive stones:catalytic activity to remove benzene from gaseous emissions[J].Journal of Physics and Chemistry of Solids,2004,65:655.
  • 4Miao Shaojun,Deng Youquan.Au-Pt/Co3O4 catalyst for methane combustion[J].Applied Catalysis B:Environmental,2001,31:L1.
  • 5Marta Maria Natile,Antonella Glisenti.Surface reactivity of NiO/Co3O4 and Fe2O3/Co3O4 nanocomposite catalysts:interaction with methanol[J].Journal of Molecular Catalysis A:Chemical,2004,217:175.
  • 6Virkar Anil V,Chen Jong,Tanner Cameron W,Kim Jai-Woh.The role of electrode microstructure on activation and concentration polarizations in solid oxide fuel cells[J].Solid State Ionics,2000,131:189.
  • 7San Ping Jiang,Wei Wang.Fabrication and Performance of GDC-impregnated (La,Sr)MnO3 cathodes for intermediate temperature solid oxide fuel cells[J].Journal of the Electrochemical Society,2005,152(7):A1398.
  • 8Yamahara Keiji,Jacobson Craig P,Visco Steven J,De Jonghe Lutgard C.Catalyst-infiltrated supporting cathode for thin-film SOFCs[J].Solid State Ionics,2005,176:451.
  • 9Jiang San Ping.A review of wet impregnation-An alternative method for the fabrication of high performance and nano-structured electrodes of solid oxide fuel cells[J].Materials Science and Engineering A,2006,418:199.
  • 10Malecki A,Malecka A,Gajershi R,Prochowska-Klisch B,Podgbrecka A.The mechanism of thermal decomposition of Co(NO3)2·2H2O[J].Journal of Thermal Analysis,1988,34:203.

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