摘要
A copper coordination polymer, {[Cu3( μ-3-CPOA)2( μ-3-PyO)2(3-PyOH)2 (H2O)4]·4H2O}n (3-CPOA2-=3-carboxylphenoxyacetate dianion, 3-PyOH=3-hydroxypyridine, 3-PyO-=pyridin-3-onato) was synthesized and char-acterized by the element analysis, IR, TG and single crystal X-ray diffraction. The title complex crystallizes in triclinic system with space group P1, a=0.906 53(18) nm, b=1.155 9(2) nm, c=1.208 0(2) nm, α=93.25(3)°, β=111.05(3)°, γ=105.62(3)° and V=1.121 0(5) nm3, Z=1, R=0.052 6, wR=0.154 8. Each copper(Ⅱ)atom displays octahedron coordination geometry incorporating 3-carboxylphenoxyacetate and pyridin-3-onato ligands, except for the Cu1 atom also involving 3-hydroxypyridine and water molecules. Two adjacent copper(Ⅱ)atoms are bridged by the tridentate 3-CPOA2- group and the tridentate pyridin-3-onato ligand, constructing a one-dimensional chain structure along b axis, with the adjacent Cu...Cu distances being 0.309 3(3) nm and 0.626 5(3) nm. CCDC: 287383.
A copper coordination polymer, {[Cu3(μ-3-CPOA)2(μ-3-PyO)2(3-PyOH)2 (H2O)4] ·4H2O}, (3-CPOA^2-=3- carboxylphenoxyacetate dianion, 3-PyOH=3-hydroxypyridine, 3-PyO-=pyridin-3-onato) was synthesized and characterized by the element analysis, IR, TG and single crystal X-ray diffraction. The title complex crystallizes in triclinic system with space group P1 a=0.906 53(18) nm, b=1.155 9(2) nm, c=1.208 0(2) nm, a=93.25(3)°, β= 111.05(3)°, y=105.62(3)° and V=1.121 0(5) nm^3, Z=1, R=0.052 6, wR=0.154 8. Each copper(Ⅱ) atom displays octahedron coordination geometry incorporating 3-carboxylphenoxyacetate and pyridin-3-onato ligands, except for the Cul atom also involving 3-hydroxypyridine and water molecules. Two adjacent copper(Ⅱ) atoms are bridged by the tridentate 3-CPOA2- group and the tridentate pyridin-3-onato ligand, constructing a one-dimensional chain structure along b axis, with the adjacent Cu... Cu distances being 0.309 3(3) nm and 0.626 5(3) nm. CCDC: 287383.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2007年第1期155-158,共4页
Chinese Journal of Inorganic Chemistry
基金
黑龙江省自然科学基金(No.B200501)
黑龙江省高校骨干教师资助项目(No.1054G036)
关键词
铜配位聚合物
晶体结构
热稳定性
copper coordination polymer
crystal structure
thermal stability