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聚氯乙烯/蒙脱土插层复合材料的制备与性能 被引量：3

Study on preparation and properties of PVC/montmorillonite imbedded composites
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摘要 利用蒙脱土(MMT)的阳离子交换特性,将十二烷基三甲基氯化铵(BS-12)引入蒙脱土层间,对蒙脱土进行有机化预处理,使蒙脱土在甲基丙烯酸甲酯(MMA)中的分散性提高。借助普通乳液聚合的方法,制备出聚甲基丙烯酸甲酯(PMMA)/蒙脱土嵌入混杂材料。对混杂材料进行XRD分析,结果表明PMMA嵌入了蒙脱土层间,使层间距明显扩大。采用熔融共混的方法制备了PVC/蒙脱土复合材料,并对其强度和韧性进行了研究。结果表明,聚甲基丙烯酸甲酯/蒙脱土嵌入混杂材料可使PVC的强度和韧性分别提高17%和489.2%。 Based on the characteristic of negative charges exchange of montmorillonite （MMT）, making the dodecyl trimethyl ammonium chloride （BS-12） imbedded in the layer of MMT, we pretreated MMT and enhanced the dispersion of MMT in MMA. By means of emulsion polymerization, PMMA organ-MMT imbedding composite was prepared. By means of XRD, analysis indicated that PMMA was imbedded in the layer of montmorillonite and the layer distance was expanded obviously. Then using melt blending method, PVC/MMT composite was prepared and the intensity, toughness were also studied. The resuits show that PMMA organ-MMT imbedding composite can respectively enhance the intensity and toughness of PVC by 17 0% and 489.2%.
作者 张惠敏 杨建宁
机构地区 河北科技大学材料科学与工程学院 河北省第四建筑公司混凝土分公司
出处 《河北工业科技》 CAS 2007年第1期24-26,29,48,共5页 Hebei Journal of Industrial Science and Technology
关键词 PVC 聚甲基丙烯酸甲酯 蒙脱土 十二烷基三甲基氯化铵 PVC PMMA montmorillonite（MMT） dodecyl trimethyl ammonium chloride
分类号 TQ316.33 [化学工程—高聚物工业]
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参考文献16

  • 1KOJIMA Y,USUKI A,KAWASUMI M,et al.One potsyn thesis of Nylon 6 clay hybrid[J].J of Polym Sci(A):Polym Chem,1993,31:1 755-1 758.
  • 2SHI H,LAN T,PINNAVAIA T J.Interfacial effects on the reinforcement properties of polymer-organclay nano-composites[J].Chem Mater,1996,(8):1 584-1 587.
  • 3FUKUSHIMA Y,INAGAKI S.Synthesis of an intercalated compound of montorillonite and polyamide[J].J of Inclusion Phenomena,1987,(5):473-482.
  • 4GIANNELLIS E P.Plymer layer silicate nanocomposites[J].Advanced Materials,1996,8(1):29-35.
  • 5VAIA R A,TEUKOLSKY R K,GIANNELIS E P.Interlayer structure and molecular environment of alkylammonium layersilicates[J].Chem Mater,1994,6:1 017-1 022.
  • 6VAIA R A,GIANNELIS E P.Lattic model of polymer melt intercalation in organicaly modified layed silicates[J].Macromolecules,1997,30:7 990-7 999.
  • 7KISHNAMOORTI R,GIANNELIS E P.Rheology of end-tethered polymerlayered silicate nano-composites[J].Macromolecules,1997,30:4 097-4 102.
  • 8MASAYA K,NAOKI H,MAKOTO K,et al.Prepartion and mechanical properties of polyproplylene clay hybrids[J].Macromolecules,1997,30:6 333-6 338.
  • 9TRILICA J,ALIACHEMJ C,FATRA N,et al.PVC/ claynanocomposites[A].SPE ANTEC[C].Arlington:Dallas Texas,2001.
  • 10WANG D Y,PARLOWD,YAO O.PVC-clay nanocom-posites:Preparation,thermal and mechanical properities[J].J Vinyl Addit Tech,2001,7(4):203-213.

二级参考文献13

  • 1NICOLAOU K C,YANG Z,LIU J J,et al.Total synthesis of taxol[J].Nature,1994,(3):30-34.
  • 2GHRIBI A,ALEEXAKIS G A,NORMANT J F.Asymmetris cleavage of chiral acetals by CuLi2,BF3 reagents[J].Tetrahedron Lett,1984,25:3 083-3 086.
  • 3WANG L,SUN X H,ZHANG Y M.Reductive coupling of aromatic carbonyl compounds to pinacols using zinc powder in aqueous media[J].J Chem Research (S),1998,(6):336-337.
  • 4RIEKE R D,KIM S H .New reagent for reductive coupling of carbonyl and imine compounds: highly reactive manganese-mediated pinacol coupling of aryl aldehydes,aryl ketones,and aldimines[J].Org Chem,1998,63:5 235.
  • 5LI C J ,MENG Y ,MA J H,et al.Manganese-mediated carbon-carbon bond formation in aqueous media:chemoselective allylation and pinacol coupling of aryl aldehydes[J].Org Chem,1998,63:7 498.
  • 6YANADA R,NEGORP N,KANADA K,et al.Reductive coupling of carbonyl compounds to pinacols by using Sm-I2-MeOH or Sm-I2-Ti(OiPr)4-MeOH systems[J].Tetrahedron Lett,1997,38:3 271-3 274.
  • 7WANG Lei,ZHANG Yong-ming.Water Accelerated SM/TMSCl reduction system:pinacolic coupling of aromatic carbonyl compounds and reductive dimerization cyclization of 1,1-dicyanoalkenes[J].Tetrahedron,1998,54:11 129-11 140.
  • 8TANSKA K,SEHGAL A C,TODA F.A new method for coupling aromatic aldehydes and ketones to produce alphaglycols using zinc-zinc dichloride in adaqueous solution and in the solid state[J].Org Chem,1990,55:2 981.
  • 9KhAN R H,MATHUR R K,GHOSH A C.Synthesis and thermal diisocyzanate of phenol-and naphthol-blocked diisocyanates[J].Synth Commun,1997,27: 2 193.
  • 10KHUEANA J M,SEHGAL A J.Synthesis and excitatory amino acid pharmacology of some novel quinoxalinediones[J].Chem Soc,Chem Commun,1994,5: 571.

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河北工业科技
2007年 第1期

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