摘要
Heck反应是一类重要的卤代芳烃烯基化、形成新的C—C键的合成反应,近几年来一直是催化化学和有机化学的研究热点.总结了最近几年来国内外Heck反应新型催化体系、不对称Heck反应、Heck反应在有机合成中的最新应用等重要研究成果,希望引起同行对Heck反应的关注.
Heck reaction is a sort of classical methodology of the vinylation of aryl halides for the construction of new C--C bond. The new efficient catalysts for Heck reaction and the applications in whole synthesis of natural production have been developed greatly these years. In this paper, the recent progress in Heck coupling reaction including catalytic systems, asymmetric syntheses and applications in organic chemistry is reviewed.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2007年第2期143-152,共10页
Chinese Journal of Organic Chemistry
关键词
HECK反应
钯
催化
不对称合成
应用
Heck reaction
palladium
catalysis
asymmetric synthesis
application
