摘要
Based on the previous investigation on beneficial introduction of holmium into magnesium alloy, the effect of gadolinium, an adjacent rare earth element, on corrosion resistance was examined. The corrosion behavior of two Mg-9Al-Gd alloys (Mg-9Al-0.45Gd and Mg-9Al-1.43Gd) was evaluated and compared with that of Mg-9Al alloy without Gd by means of specimen mass loss and hydrogen evolution in 3.5% NaCl solution saturated with Mg(OH)2. The Gd-containing alloys exhibit enhanced corrosion resistance with respect to the plain Mg-9Al alloy. The microstructures of Mg-9Al alloy and Mg-9Al-0.45 Gd alloy were observed by electron probe microanalysis (EPMA) and energy dispersion spectroscopy (EDS). The alloys with Gd addition show a microstructure characterized by a phase solid solution, surrounded by minor amount ofβphase and more grain-like Gd-containing phase. To illustrate the involved mechanism their polarization curves were recorded. The electrochemical investigations reveal that Gd addition shifts the corrosion potential of the alloy towards active, as Gd containing phase is more active and hence less cathodic. As a result, the micro-galvanic corrosion is suppressed. Moreover corrosion product films formed on the Gd containing alloys are more compact and provide a better protective effectiveness than that on the alloy without Gd against corrosion. Repassivation measurements in mixture solution of 0.21 mol/L K2CrO4+0.6 mol/L NaCl also verify the beneficial role of Gd addition. Based on the present preliminary analysis, both the deposited Gd-containing phases and corrosion product films are believed to be responsible for the improved corrosion behaviour due to Gd addition.
Based on the previous investigation on beneficial introduction of holmium into magnesium alloy, the effect of gadolinium, an adjacent rare earth element, on corrosion resistance was examined. The corrosion behavior of two Mg-9Al-Gd alloys (Mg-9Al-0.45Gd and Mg-9Al-l.43Gd) was evaluated and compared with that of Mg-9Al alloy without Gd by means of specimen mass loss and hydrogen evolution in 3.5% NaCl solution saturated with Mg(OH)2. The Gd-containing alloys exhibit enhanced corrosion resistance with respect to the plain Mg-9Al alloy. The microstructures of Mg-9Al alloy and Mg-9Al-0.45 Gd alloy were observed by electron probe microanalysis (EPMA) and energy dispersion spectroscopy (EDS). The alloys with Gd addition show a microstructure characterized by a phase solid solution, surrounded by minor amount of β phase and more grain-like Gd-containing phase. To illustrate the involved mechanism their polarization curves were recorded. The electrochemical investigations reveal that Gd addition shifts the corrosion potential of the alloy towards active, as Gd containing phase is more active and hence less cathodic. As a result, the micro-galvanic corrosion is suppressed. Moreover corrosion product films formed on the Gd containing alloys are more compact and provide a better protective effectiveness than that on the alloy without Gd against corrosion. Repassivation measurements in mixture solution of 0.21 mol/L K2CrO4+0.6 mol/L NaCI also verify the beneficial role of Gd addition. Based on the present preliminary analysis, both the deposited Gd-containing phases and corrosion product films are believed to be responsible for the improved corrosion behaviour due to Gd addition.
出处
《中国有色金属学会会刊:英文版》
CSCD
2006年第A03期1664-1668,共5页
Transactions of Nonferrous Metals Society of China
基金
Project(045211028) supported by Shanghai Science & Technology Development Fund, China
关键词
金属腐蚀
镁合金
稀土元素
微观结构
AZ91D alloy
magnesium alloy
corrosion
gadolinium
rare earth