N－（β－叠氮乙基）－2，4，6－三硝基苯胺的合成

Synthesis of N-(β-Azidoothyl)-2, 4, 6-Trinitroaniline

以２，４，６－三硝基氯苯（苦基氯）或２，４，６－三硝基苯甲硝胺（特屈儿）为基质，通过亲核取代反应，用三种方法合成了Ｎ－（β－叠氯乙基）－２，４，６－三硝基苯胺，并以红外、氢核磁、化学电离质谱及元素分析鉴定了此化合物的结构．在所采用的三种方法中，以方法（Ⅱ）为优，工艺简便，反应时间短，产品得率高．

N-(β-azidoethyl)-2, 4, 6-trinitroaniline was synthesized by three mehtods via nucleophilic substitution reaction using 2, 4, 6-trinitrochlorobenzene (picryl chloride) or 2, 4, 6-trinitrophenyl methylnitramine (tetryl) as substrate. The prepared compound has been identified by IR, 1HNMR, MS(CI) and elemental analysis. Among the three methods, the second one possesses the following advantages:simple,short reaction time and high yield.