期刊文献+

应用OBM模型研究广州臭氧的生成过程 被引量:24

Process Analysis of Ozone Formation in Guangzhou: Application of Observation-Based Model
下载PDF
导出
摘要 应用基于观测的模型(OBM)研究了广州及其周边地区2000年夏、秋季臭氧生成过程的相对敏感性.在分析2000年7,11月广州市环境保护研究所及其下风向的花都和新垦地区臭氧及其前体物浓度变化和相互关系基础上,应用OBM模型对上述地点的光化学反应过程进行了初步的模拟分析,以讨论这一地区的光化学反应类型.研究表明:7月广州市环境保护研究所RIR(AHC)>RIR(NO),臭氧生成处于VOC控制,下风向的花都RIR(NO)>RIR(AHC),臭氧生成处于NOx控制;11月广州市环境保护研究所RIR(AHC)>RIR(NO),臭氧生成处于VOC控制,下风向的新垦RIR(NO)>RIR(AHC),臭氧生成处于NOx控制.该模拟结果与该地区的相关空气质量模型研究结果具有可比性. An observation-based model (OBM) was used to analyze the process of ozone formation in Guangzhou area in the summer and autumn of 2000. The concentration change and relations of ozone and its precursors at Guangzhou Environmental Protection Institute (GEPI) and two downwind suburban areas, Huadu and Xinken, in July and November 2000 were analyzed, On this basis, the OBM was applied to preliminarily simulate the photochemical process and discuss the type of photochemical reaction at these areas. The results showed : in July, the relative incremental reactivity (RIR) of AHC was greater than that of NO and the ozone formation was in VOC-control condition at GEPI, while the RIR of NO was greater than that of AHC and the ozone formation was in NOx-contrel condition at its downwind Huadu; in November, the RIR of AHC was greater than that of NO and the ozone formation was in VOC-control condition at GEPI, while the RIR of NO was greater than that of AHC and the ozone formation was in NOx-control condition at its downwind Xinken. The results were comparable to those applied with AQM method in this region.
出处 《环境科学研究》 EI CAS CSCD 北大核心 2007年第1期47-51,共5页 Research of Environmental Sciences
基金 国家重点基础研究发展计划(973)项目(2002CB410801)
关键词 基于观测的模型(OBM) 臭氧生成潜势 相对增量反应性(RIR) observation-based model (OBM) ozone production potential relative incremental reactivity (RIR)
  • 相关文献

参考文献8

  • 1Cardelino C,Chameides W L.An observation-based model for analyzing ozone-precursor relationships in the urban atmosphere[J].J Air Waste Manag Assoc,1995,45:161-180.
  • 2Cardelino C,Chameides W L.The application of data from photochemical assessment monitoring stations to the observation-based model[J].Atmos Environ,2000,34:2325-2332.
  • 3Kleinman L I.Ozone process insights from field experiments part Ⅱ:observation-based analysis for ozone production[J].Atmos Environ,2000,34:2023-2034.
  • 4王伯光,张远航,邵敏.珠江三角洲大气环境VOCs的时空分布特征[J].环境科学,2004,25(S1):7-15. 被引量:96
  • 5Chameides W L,Fehsenfeld F.Ozone precursor relationships in the ambient atmosphere[J].Journal of Geophysical ResearchAtmospheres,1992,97:6037-6056.
  • 6付琳琳,邵敏,刘源,刘莹,陆思华,汤大钢.机动车VOCs排放特征和排放因子的隧道测试研究[J].环境科学学报,2005,25(7):879-885. 被引量:47
  • 7邵敏,任信荣,王会祥,曾立民,张远航,唐孝炎.城市大气中OH和HO_2自由基生成和消除的定量关系[J].科学通报,2004,49(17):1716-1721. 被引量:21
  • 8Roger Atkinson,Janet Arey.Atmospheric degradation of volatile organic compomds[J].Chemical Reviews,2003,103:4605-4638.

二级参考文献47

  • 1张靖,邵敏,苏芳.北京市大气中挥发性有机物的组成特征[J].环境科学研究,2004,17(5):1-5. 被引量:105
  • 2李金龙,白郁华,胡建信,邵敏,张宝祥,夏羽,唐孝炎.油松排放萜烯类化合物浓度的日变化及排放速率的研究[J].中国环境科学,1994,14(3):165-169. 被引量:30
  • 3Thompson A M.The oxidizing capacity of the earth's atmosphere:probable past and future changes.Science,1992,256:1157 ~ 1165
  • 4Holland F,Aschmutat U,Heβling M,et al.Highly time resolved measurements of OH during the POPCORN using laser-induced fluorescence spectroscopy.Journal of Atmospheric Chemistry,1998,31(1/2): 205~ 225
  • 5Mauldin R L,Frost G J,Chen G,et al.OH measurements during the first aerosol characterization experiment (ACE 1): observations and model comparisons.Journal of Geophysical Research,1998,103(D13): 16713 ~ 16729
  • 6Kley D,Kleinmann M,Sanderman H,et al.Photochemical oxidants:state of the science.Environmental Pollution,1999,100:19 ~ 42
  • 7Ehhalt D H,Rohrer E.Dependence of the OH concentration on solar UV.Journal of Geophysical Research,2000,105:3565 ~ 3571
  • 8Faloona I.Observations of HOx and its relationship with NOx in the upper troposphere during SONEX.Journal of Geophysical Research,2000,105:3771 ~ 3783
  • 9Jenkin M E,Sandra M S,Pilling M J.The tropospheric degradation of volatile organic compounds: a protocol for mechanism development.Atmospheric Environment.1997,31(1): 81 ~ 104
  • 10Atkinson R,Lloyd A C,Winges L.An updated chemical mechanism for hydrocarbon/NOx/SO2 photo-oxidations suitable for inclusion in atmospheric simulation models.Atmospheric Environment,1982,16(6): 1341 ~ 1355

共引文献153

同被引文献346

引证文献24

二级引证文献599

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部