摘要
采用非均相吸附法制备了壳聚糖铁(Ⅲ)配合物,用紫外光谱(UV)、红外光谱(IR)对配合物的结构进行了表征;研究了壳聚糖对Fe3+的吸附动力学特性。实验结果表明,壳聚糖与Fe3+之间发生了配位作用,壳聚糖分子中参与配位反应的主要是-NH2、-OH及少量的-NHCOCH3;壳聚糖对Fe3+的吸附行为可用Langmuir单分子层吸附机理解释,且求得吸附表观活化能为3.6476kJ/mol。
In this paper the structure of the chitcsan-ferric（CTS-Fe^3＋） complex prepared by non-homogeneous adsorption was confirmed by IR and UVspectra, and the isothermal adsorption kinetics of CTS for ferric ions has also been investigated. The experiments indicated that the chelate reaction occurrs between - NH2,- OH,-NHCOCH3 of CTS and ferric ions, the adsorption is satisfied with the Langmuir-single-molecule-layer adsorption mechanism, and the apparent adsorption activation energy is 3.6476kJ/mol.
出处
《食品科学》
EI
CAS
CSCD
北大核心
2007年第1期63-67,共5页
Food Science
