摘要
2-(1,3-亚丙二硫基)亚甲基环己酮(1)与2-甲基烯丙基氯化镁加成得α-羟基烯酮二硫缩酮类化合物(2).在各种开链脂肪醇存在下,(2)经酸催化的取代-环合芳构化反应生成酚醚类化合物(3).
Dithopropylene)methylene cyclohexanone(1)rcacted with methallyl Grignard reagent produced the carbinol(2).Catalyzed by acid and in the presence of alcohols,(2)were converted to the aryl ethers(3)via the Substitution-Cycloaromatization Reaction.
出处
《东北师大学报(自然科学版)》
CSCD
1996年第3期55-57,共3页
Journal of Northeast Normal University(Natural Science Edition)
关键词
氧代烯酮
二硫代缩酮
酚醚
合成
亚甲基环己酮
Dithlopropylene) methylene cyclohexanone
substitution-cycloarom atization reaction
aryl ethers
synthesis