摘要
In2O3 octahedrons were synthesized by carbothermal reduction using In2O3 nanoparticles as the source material. The as-synthesized products were characterized by X-ray powder diffraction (XRD), energy dispersive X-ray(EDX), scanning electron microscopy(SEM), transmission electron microscopy(TEM), high-resolution transmission electron microscopy (HRTEM), selected-area electron diffraction analysis(SAED) and Room-temperature photoluminescence(PL) spectroscopy. The results show that the products are single-crystalline In2O3 octahedrons, the length of the octahedrons is in the range of 400~3 000 nm; the PL patterns display two peaks located at 447nm and 555 nm upon excitation at 380 nm, and the other two peaks located at 444 nm and 550 nm upon excitation at 325 nm; the excitation pattern shows two peaks located at 274 nm and 371 nm, respectively. The growth mechanism of the In2O3 octahedrons is discussed, and the high supersaturation ratio is considered as the key factor.
In2O3 octahedrons were synthesized by carbothermal reduction using In2O3 nanoparticles as the source material. The as-synthesized products were characterized by X-ray powder diffraction （XRD）, energy dispersive X- ray （EDX）, scanning electron microscopy （SEM）, transmission electron microscopy （TEM）, high-resolution transmission electron microscopy （HRTEM）, selected-area electron diffraction analysis （SAED） and Roomtemperature photoluminescence （PL） spectroscopy. The results show that the products are single-crystalline In2O3 octahedrons, the length of the octahedrons is in the range of 400-3 000 nm; the PL patterns display two peaks located at 447nm and 555 nm upon excitation at 380 nm, and the other two peaks located at 444 nm and 550 nm upon excitation at 325 nm; the excitation pattern shows two peaks located at 274 nm and 371 nm, respectively. The growth mechanism of the In2O3 octahedrons is discussed, and the high supersaturation ratio is considered as the key factor.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2007年第3期499-503,共5页
Chinese Journal of Inorganic Chemistry
基金
广西自然科学基金(No.桂科基0575030
桂科基0639025)资助项目
