摘要
研究了葡醛内酯、盐酸美司坦和重酒石酸去甲肾上腺素等10种物质在高碘酸钾-鲁米诺体系中的后化学发光现象、后化学发光反应的动力学、化学发光光谱、荧光光谱以及其它相关性质,提出了其可能的发光机理;在优化的分析条件下建立了这10种物质的后化学发光分析方法,初步构建了高碘酸钾-鲁米诺后化学发光分析体系.
The post-chemiluminescence （PCL） reactions of glucuronolactone, mecysteineh hydrochloride, isoniazid, dopamine hydrochloride, lincomycin hydrocholoride, hydrocortisone, amoxicillin, antondine, adrenaline hydrochloride and noradrenaline bitartrate in potassium periodate-luminol system were discovered. The possible mechanism for the PCL reaction was discussed via the investigation of the CL kinetic characteristics, the chemiluminescence reaction（CL） spectra and the fluorescence spectra of some related substances. The flow injection PCL method for the determination of the 10 kinds of substances was established. The post-chemiluminescence analytical system based on potassium periodate-luminol reaction was established.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2007年第3期436-440,共5页
Chemical Journal of Chinese Universities
基金
国家自然科学基金(批准号:20275023)资助
关键词
后化学发光反应
高碘酸钾
鲁米诺
Post-chemiluminescence reaction
Potassium periodate
Luminol
