对金属阳离子变形性的讨论

Discusses on the Variability of Positive Ionic Shape

根据改进了的Ｓｌａｔｅｒ规则计算了阳离子价层中最高占有轨道、最低空轨道的能量和Ｃｌ~－、Ｏ^（２－）阴离子价层轨道能量．结合能量相近原理分析了离子变形过程及电子密度，得出了阳离子变形性与离子构型间的关系为：８电子型＜９～１７，１８电子型＜１８＋２电子型．这一结果与有关文献相符．

The energies of the lowest energy orbits, not filled with electrons, of positive ionsand of the highest energy orbits, filled with electrons, of Cl-and O2-have been calculated by usingbettered Slater rule. By connecting princple and discussing the processes of ionic polarization, andanalysing the density of electron of positive ions, the relativity between ionic structure and the Variability of ionic shape: 8<9～17, 18<M 18 + 2 is introduced, the rule corresponds to with relativedrefrence materials.