摘要
本文用X射线衍射(XRD)和高分辨电镜研究Co薄膜在氩气气氛或真空条件下热处理时Co/Si和Co/SiO2体系的界面反应.结果表明:在氩气氛下450℃处理时,Co薄膜均发生氧化,在Co/Si界面同时有硅化物形成,而在Co/SiO2界面,无硅化物产生.在真空条件下500℃处理1小时,薄膜没有氧化,在Co/Si界面形成完整的CoSi2外延层.
Abstract We have investigated the Co/Si and Co/SiO2 interface reaction of the vaccum or Ar-annealed Co films using XRD and HREM techniques. The results showed that annealed at 450℃ under Ar ambient Co film was oxidized and silicide was observed at Co/Si interface but not at Co/SiO2 interface. Annealed at 50℃ for an hour under the vacuum condition,Co film was not oxidized and perfect epitaxial CoSi2 layer was formed at the Co/ Si interface.