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聚(N-取代吡咯)的合成及性能 被引量:1

Preparation and Property of Poly(N-Substituted Pyrrole)
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摘要 制备了5种N-取代吡咯衍生物:N-丁基吡咯、N-辛基吡咯、N-十二烷基吡咯、N-十六烷基吡咯、N-十八烷基吡咯,用化学氧化法对其实施了聚合反应,最终得到黑色粉末状产物,其电导率均在10^(-4)以下。通过FT-IR、元素分析等手段对聚合物进行了表征. N-Alkyl pyrroles(alkyl:butyl,octyl,lauryl,cetyl,stearyl)have been prepared and polymerized by chemical oxidation respectively.The ultimately obtained product is a black powder.The electrical conductivity of the polymers is less than 1 0-4S/cm.The polymers were charactered by means of FT-IR and analysis of elements.
出处 《沈阳化工学院学报》 1996年第4期263-267,共5页 Journal of Shenyang Institute of Chemical Technolgy
基金 辽宁省科委资助
关键词 导电聚合物 取代吡咯 掺杂 聚吡咯 conductive polymer N-substituted pyrrole dope
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同被引文献8

  • 1邓伯华,庞代文.N-取代吡咯共聚物及其制备方法和用途[P].2002;(8):21.
  • 2Lainton J.A.H., Hoffman .I.W., Martin B.R. and Compton D.R., 1-Alkyl-3-(1-naphthoyl)pyrroles: A new class of cannabinoid [J] Tetrahedron Lett.,1995,36:1401-1404.
  • 3Dieter R.K, H.Y. Yu. A facile synthesis of polysubstituted pyrroles [J] Org. Lett., 2000. 2(15): 2283-2286.
  • 4Iwasawa N., Maeyama IC and Saitou M., Reactions of Propargyl Metallic Species Generated by the Addition of Alkynyllithiums to Fischer-Type Carbene Complexes [J] J. Am. Chem. Soc., 1997, 119: 1486-1487.
  • 5Furstner A., Wcintritt H. and Hupperts A., A New, Titanium-Mediated Approach to Pyrroles: First Synthesis of Lukianol Aand Lamellarin O Dimethyl Ether[J].J. Org. Chem., 1995, 60: 6637-6641.
  • 6Katritzky A., Jiang J. and Steel P.J., 1-A,za-1,3-bis(triphenylphosphoranylidene)propane: A Novel :CHCH2N: Synthon [J] J. Org. Chem., 1994, 59: 4551-4555.
  • 7Ruault P., Pilard J.-E, Touaux B., Bouilet ET.and Hamelin J., Rapid Generation of Amines by Microwave Irradiation of Ureas dispersed on Clay [J] Synlett, 1994,(11): 935-936.
  • 8Frydman B.; Ojea M.I,. 1,4-Diaminobutancs from furans: A new synthetic approach to substituted putrescines[J] Tetrahedron Lett., 1998, 39(27): 4765-4768.

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