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5-(对-羟基苯基)-10,15,20-三苯基卟啉的金属化及性质表征 被引量：5

Metallization and Characterization of meso-5-(p-hydroxyphenyl)-10,15,20-triphenylporphyrin
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摘要 设计、合成、分离了5-(对羟基苯基)-10,15,20-三苯基卟啉化合物,并合成其金属配合物.通过元素分析,IR,UV-vis和1HNMR等方法确证了这些化合物的结构,给出了卟啉类配体与金属配合物的IR,UV-vis和1HNMR判据,并对它们的热稳定性质进行了研究. Different transition metalloporphyrins （ Mn, Fe, Co, Ni, Cu, Zn） were prepared, purified and they were characterized by means of element analysis, IR, UV-vis and 1^ HNMR. The correlation between the structures of the compounds and their 1^HNMR, IR, UV spectra was discussed and their specific spectra were explained. The thermostabilities of the compounds were studied with the aid of TGA-TDA.
作者 单凝 郑文琦 法焕宝 王杏乔
机构地区 吉林大学化学学院
出处 《吉林大学学报（理学版）》 CAS CSCD 北大核心 2007年第2期283-287,共5页 Journal of Jilin University:Science Edition
基金 国家自然科学基金(批准号:20071014)
关键词 金属卟啉 表征 差热热重 metalloporphyrins characterization TGA-TDA thermogram
分类号 O614 [理学—无机化学]
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参考文献15

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二级参考文献21

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共引文献41

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引证文献5

二级引证文献14

吉林大学学报（理学版）
2007年 第2期

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