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pH值、无机电解质对PAE和CMC在纤维上吸附量的影响 被引量:3

Effect of pH and Electrolyte Concentration on the Adsorption of PAE and CMC on Pulp Fibers
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摘要 通过测量纸浆Zeta电位以及聚合电解质的吸附量等方法,研究了pH值和无机电解质对阳离子聚酰胺-环氧氯丙烷树脂(PAE)和阴离子羧甲基纤维素(CMC)在纤维表面吸附量的影响。实验结果证明吸附量随纸浆悬浮液中无机电解质浓度的升高先增大后减小;随pH值的升高而增大。 The adsorption characteristics of high polyamideamine epichlorohydrine and carboxymethylcellulose on pulp fibers were studied in this paper. In experiment, the pulp's Zeta potential and polyelectrolytes' adsorption quantity were measured. The conclusion is that polydectrolytes' adsorption on pulp fibers can be improved by increasing electrolyte concentration at low level, and decreased on further addition of electrolyte; polyelectrolytes' adsorption can be improved by increasing pH of PULP.
出处 《纸和造纸》 北大核心 2007年第2期39-42,共4页 Paper and Paper Making
基金 国家自然科学基金(20576102) 华南理工大学制浆造纸工程国家重点实验室开放基金(200405)。
关键词 聚酰胺-环氧氯丙烷树脂 羧甲基纤维素 胶体滴定 ZETA电位 polyamideamine epichlorohydrine carboxymethylcellulose Colloid Titration Zeta potential
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参考文献4

  • 1R Hendrickson,D Neuman.The influence of simple electrolytes on polyacrylamide adsorption by hardwood kraft pulps[J].Tappi Journal,1985,68 (11):120-125.
  • 2G Ladam,P Schaad,C J Voegel,et al.In situ determination of the structural properties of initially deposited polyelectrolyte multiayers[J].Langmuir,2000,16(3):1249-1255.
  • 3T Lindstrom,L Wagberg.Effect of pH and electrolyte concentration on the adsorption of cationic polyacryamides on cellulose[J].Tappi Journal,1983,66(6):83-85.
  • 4P Mocchiutti,M A Zanuttini.A useful equation for estimating the surface charge of pulp fibers[J].Tappi Journal,2005,4(5):18-22.

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