摘要
The title compound, [Mn4O2(O2CMe)6(MeOH)2(dbm)2]·2MeCOOH·2CH2Cl2 (Hdbm = dibenzoylmethane), has been synthesized and structurally determined by single-crystal X-ray diffraction. The crystal belongs to triclinic, space group P/, with a = 10.729(3), b = 12.269(3), c = 13.085(4) A, a = 106.367(3),β = 107.643(2), γ = 94.771(2)°, V = 1547.9(7) A^3, Z = 1, C50H64Cl4Mn4O24, Mr= 1410.57, Dc= 1.513 g/cm^3, F(000) = 724, Rint = 0.0147, T= 293(2) K and p = 1.046 mm ^-1. The final R = 0.0359 and wR = 0.0938 for 5791 observed reflections with 1 〉 2σ(/). The structure of the complex consists of one [Mn4(μ3-O)2]^8+ core with four coplanar Mn atoms disposed in an extended "butterfly-like" arrangement and two O atoms triply bridging each "wing", and the peripheral ligation is provided by six by-MeCO2^-, two terminal ,μ2-dbm- groups at the two ends of the molecule, and two MeOH molecules on the central Mn atoms, lntermolecular O…H-O hydrogen bonding interactions are found within the structure of the compound.
The title compound, [Mn4O2(O2CMe)6(MeOH)2(dbm)2]·2MeCOOH·2CH2Cl2 (Hdbm = dibenzoylmethane), has been synthesized and structurally determined by single-crystal X-ray diffraction. The crystal belongs to triclinic, space group P/, with a = 10.729(3), b = 12.269(3), c = 13.085(4) A, a = 106.367(3),β = 107.643(2), γ = 94.771(2)°, V = 1547.9(7) A^3, Z = 1, C50H64Cl4Mn4O24, Mr= 1410.57, Dc= 1.513 g/cm^3, F(000) = 724, Rint = 0.0147, T= 293(2) K and p = 1.046 mm ^-1. The final R = 0.0359 and wR = 0.0938 for 5791 observed reflections with 1 〉 2σ(/). The structure of the complex consists of one [Mn4(μ3-O)2]^8+ core with four coplanar Mn atoms disposed in an extended "butterfly-like" arrangement and two O atoms triply bridging each "wing", and the peripheral ligation is provided by six by-MeCO2^-, two terminal ,μ2-dbm- groups at the two ends of the molecule, and two MeOH molecules on the central Mn atoms, lntermolecular O…H-O hydrogen bonding interactions are found within the structure of the compound.
基金
the NNSFC (No. 20471061)
the Science & Technology Innovation Foundation for the Young Scholar of Fujian Province (No. 2005J059)