固相化学反应研究（Ⅵ）──Mossbauer谱法研究室温氧化还原

Solid State Redox Reaction of [Fe(phen)_3](ClO_4)_3·H_2O with Sodium Iodide at Room Temperature

本文研究室温下［Ｆｅ（ｐｈｅｎ）３］（ＣｌＯ４）３·Ｈ２Ｏ与ＮａＩ发生的固－固相氧化还原反应。用Ｍｓｓｂａｕｅｒ谱、ＸＲＤ、ＩＲ、元素分析、ＴＧ－ＤＴＡ和磁化率测定等手段表征了反应２４ｈ后的固相产物，并采用反应截面移动法研究了等温固相反应动力学。结果表明，室温下该反应速度快、进行完全。

In this paper,the solid state redox reaction of [Fe(phen)3](ClO4)3·H2O with sodium iodide was studied at room temprature.Mossbauer spectrometry,XRD,IR,TG-DTA and Elemental analysis were used to characterize the solid product.