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A New Approach to C60-Containing Polyphosphazenes by Polymerization of Phosphonitrile Chloride Trimer in the Presence of C60

A New Approach to C60-Containing Polyphosphazenes by Polymerization of Phosphonitrile Chloride Trimer in the Presence of C60
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摘要 A novel synthetic strategy was developed to prepare polyphosphazenes containing C60 moieties. Thus, the phosphonitrile chloride trimer underwent thermal ring-opening polymerization (ROP) in the presence of C60 molecules to yield the reactive macromolecular intermediate, C60-containing poly(dichlorophosphazene). And then, the other groups could be linked to the phosphazene backbone by nucleophilic substitution reaction of the chlorine atoms in this intermediate to produce a series of C60-containing polyphosphazene. The polymer exhibits good solubility in common organic solvents and is thermally stable. A novel synthetic strategy was developed to prepare polyphosphazenes containing C60 moieties. Thus, the phosphonitrile chloride trimer underwent thermal ring-opening polymerization (ROP) in the presence of C60 molecules to yield the reactive macromolecular intermediate, C60-containing poly(dichlorophosphazene). And then, the other groups could be linked to the phosphazene backbone by nucleophilic substitution reaction of the chlorine atoms in this intermediate to produce a series of C60-containing polyphosphazene. The polymer exhibits good solubility in common organic solvents and is thermally stable.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2007年第3期406-410,共5页 中国化学(英文版)
基金 Project supported by the National Natural Science Foundation of China (No. 20674059).
关键词 POLYPHOSPHAZENE synthesis C60 polyphosphazene, synthesis, C60
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