钯的氧膦络合物催化氯苄双羰基化反应的研究

Double Carbonylation Reaction of C_6H_5CH_2Cl Catalyzed by Palladium Complexes

本文研究了用两种含氧膦配体的钯络合物作为均相催化剂的氯苄双羰基化反应。考察了反应温度、压力、催化剂用量对生成苯基丙酮酸甲酯产率及选择性的影响。

Double carbonylation reaction of C6H5CH2Cl has been studied by using Pdcomplexes with phosphino ligands as homogeneous catalyst.The effect of reaction tempera-ture, Pressure and using quantity of catalyst on the yield and selectivity of the reaction prod-uct C6H5CH2COCOOCH2 was also discussed.