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高吸水树脂的溶胀动力学 被引量:7

Swelling Kinetics of Super-Absorbent Polymer
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摘要 基于扩散-松弛模型,分别研究了树脂粒度和溶液浓度对高吸水树脂溶胀行为的影响。实验结果表明:水分子的扩散和树脂大分子链段的松弛对树脂的溶胀均有贡献,但两者贡献大小与树脂粒度和溶液浓度有关。 Based on a diffusion-relaxation model, the influence of particle size and solution concentration on super-absorbent polymer(SAP) swelling kinetics is studied in this paper. The diffusion of water molecule and the relaxation of the chains of the polymer both contribute to the SAP swelling, but the SAP size and the solution concentration play more important roles.
出处 《功能高分子学报》 CAS CSCD 北大核心 2007年第1期113-116,共4页 Journal of Functional Polymers
关键词 高吸水树脂 溶胀动力学 浓度 super-absorbent polymer, swelling kinetics, concentration
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参考文献4

  • 1Fatima Rosa,Joao Bordado,Miguel Casquilho.Kinetics of water absorbency in AA/AMPS copolymers:Applications of a diffusion-relaxation model[J].Polymer,2002,43:63-70.
  • 2Sun Yi-Ming.Sorption/desorption properties of water vapour in poly(2-hydroxyethyl methancrylate):2.Two-stage sorption models[J].Polymer,1996,37(17):3921-3928.
  • 3Nancy M Franson,Nikolaos A Peppas.Influence copolymer composition on non-Fickian water transport through glassy copolymers[J].J Applied Polymer Science,1983,28:1299-1310.
  • 4Ryo Yoshida,Yukinari Okuyama,Kiyotaka Sakai,et al.Sigmoidal swelling profiles for temperature-responsive poly(N-isopropylacrylamide-co-butyl methacrylate)[J].J Membrane Science,1994,89:267-277.

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