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直接甲醇燃料电池膜及阴极模拟 被引量:1

MEMBRANE AND CATHODE NUMERICAL SIMULATION OF A DIRECT METHANOL FUEL CELLS
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摘要 本文提出一个针对直接甲醇燃料电池膜及阴极的二维、多组分稳态数学模型.模型根据直接甲醇膜燃料电池膜及阴极运行工况特性,考虑质量、动量、组分守恒以及电池中的电化学过程而建立,并应用了计算流体动力学(CFD)技术.模拟结果表明传质对直接甲醇燃料电池的性能影响很大;本文还进行了直接甲醇燃料电池阴极水管理的初步探讨. A two-dimension, multicompoment steady-state numerical simulation approach is presented to evaluation a direct methanol fuel cells (DMFC). The model is applied to simulate the membrane and the cathode sides of DMFC. The model is based on the conservation of mass, momentum, species, and combines the electrochemistry process in the DMFC. The numerical model is created using an advanced computational fluid dynamics (CFD) technique. The simulative results reveal that: the mass transfer has great influence on the performance of DMFC. The water management in DMFC was analyzed simply.
出处 《工程热物理学报》 EI CAS CSCD 北大核心 2006年第6期1017-1019,共3页 Journal of Engineering Thermophysics
基金 国家自然科学基金资助项目(No.50236010No.50406010 No.50028605) 北京工业大学校青年基金项目(No.JQ0504200363)
关键词 燃料电池 直接甲醇 阴极 质子交换膜 数值模拟 fuel cell direct methanol cathode proton exchange membrane numerical simulation
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参考文献2

  • 1Guo H,Ma C F,Wang M H,et al.Heat and Mass Transfer and Two Phase Flow in Hydrogen Proton Exchange Membrane Fuel Cells and Direct Methanol Fuel Cells.In:Proceedings of First International Conference on Fuel Cell Science,Engineering and Technology,Rochester,NY:ASME,2003.471-476
  • 2Xue-Dong Din,Efstathios E Michaelides.Transport Processes of Water and Protons Through Micropores.AIChE Journal,1998,44(1):35-47

同被引文献6

  • 1詹姆斯·拉米尼,安德鲁·迪克斯[美].燃料电池系统原理·设计·应用[M].北京:科学出版社,2006.
  • 2Kulikovsky A A, Divisek J, Komyshev A A. Two-dimensional simulation of direct methanol fuel cell: a new(embedded) type of current collector [ J ]. Journal of the Electrochemical Society, 2000, 147(3) :953--959.
  • 3Ingham D B, Pop I. Transport phenonmena in porous media [M]. Oxford: Elsevier Science Ltd, 2002.
  • 4Hogarth M, Christensen P, Hamnett A, et al. The design and construction of high-performance direct methanol fuel cells( 1 ) Liquid-feed systems[J]. Journal of Power Sources, 1997, 69 (1-2) : 113--124.
  • 5Krewer U, Song Y, Sundmacher K, et al. Direct methanol fuel cell (DMFC) : analysis of residence time behaviour of anode flow bed [J]. Chemical Engineering Science, 2004, 59: 119 --130.
  • 6Kai Sundmacher, Keith Scott. Direct methanol polymer electrolyte fuel cell: Analysis of charge and mass transfer in the vapour-liquid-solid system [J]. Chemical Engineering Science, 1999, 54:2927--2936.

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