摘要
本文讨论了PbO—Bi2O3—B2O3玻璃中引入少量Cr2O3对玻璃的颜色及析晶性能的影响。在PbO—Bi2O3—B2O3玻璃的配合料引入0.01—2(wt%)的Cr2O3随着Cr2O3含量的变化,玻璃颜色从橙黄、橙红到深红变化,直至析晶、失透。当Cr2O3引入量在0.25~0.5(wt%)时,适当控制热处理条件,可得到含有粗大晶体的红色玻璃,EDS测试表明,析出矿物的化学组成为Al和K,其原子比为1:1。
This paper deals with the coloration and nucleation effects of PbO-Bi2O-B2O3 glass with trace amount of Cr2O3 addition . The experimental results showed that thevariation of color from yellow. orange, red . dark brown to total devitrification were appearedwit the addition of 0. 01 ̄2 (wt%) Cr2O3 With the suitable control of heat treatment. heavycrystallization was produced with 0. 25 ̄0. 5 (wt%) Cr2O3 added. The EDS measurementshowed that the nucleated compound contens Al and K with atomic ratio of 1: 1.