程序控温动态分析对聚醚醚酮结构特征的研究（Ⅱ）探针分子四氢呋喃对PEEK结构的研究

A Study on the Structural Characteristic of PEEK by Temperature Programmed Dynamic Analysis (Ⅱ)A Study on the Structure of PEEK with Tetrahydrofuran as Probe Molecules

采用程序控温动态分析方法．以四氢呋喃为探针分子，通过考察四氢呋喃分子在ＰＥＥＫ样品上的程序升温解吸（ＴＰＤ）行为，讨论了不同ＰＥＥＫ样品的结构特征．结果发现：探针分子与ＰＥＥＫ的相互作用受ＰＥＥＫ结构特征的影响；由探针分于四氢呋喃与ＰＥＥＫ的作用强度及与ＰＥＥＫ作用的探针分子量，可判断不同ＰＥＥＫ样品分子结构和结晶结构的差异．

The structural characteristics of various samples PEEK are studied by temperature programmed desorption with tetrahydrofuran as probe molecules. The results show that the interaction between PEEK and probe molecules is influenced by the structure of PEEK, the differences in the molecular structure and the crystalline structure amohg various PEEK samples can be distinguished by the interacting intensities of the PEEK and tetra hydrofuran and the quantities of the probe molecules.