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光催化分解水制氢的临界光能转换效率 被引量:1

Critical conversion efficiency of light energy of the photocatalytic hydrogen production from water decomposition
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摘要 为了确定在能量转换上有价值的光催化分解水制氢过程,提出了临界光能转换效率的概念。临界光能转换效率就是系统产出的氢能与外界输入系统的能量相等时的光能转换效率。只有当光能转换效率超过其临界光能转换效率的时候才有可能实现系统的能量收益。对使用Na2S/Na2SO3作为牺牲剂的体系进行了分析计算,结果显示在年产2万t氢气规模下,该系统的临界光能转换效率为13%。 The idea of the critical conversion efficiency is suggested to improve the conversion efficiency of light energy. The critical conversion efficiency is defined as the conversion efficiency of light energy when the hydrogen energy output is equal to the energy input from the outside system. The energy profit cannot be achieved until the conversion efficiency of light energy is greater than the critical value. A system with Na2S/Na2SO3 as sacrificial reagent is analyzed and calculated. The results show that the critical conversion efficiency of light energy reaches 13 % when the annual hydrogen production is 20, 000 tons.
作者 毛文轶 冯霄
出处 《华北电力大学学报(自然科学版)》 CAS 北大核心 2007年第2期45-47,共3页 Journal of North China Electric Power University:Natural Science Edition
基金 国家重点基础研究发展规划资助项目(2003CB214500)
关键词 光催化 分解水 制氢 临界光能转换效率 photocatalytic water decomposition hydrogen production critical conversion efficiency of light energy
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参考文献13

  • 1Fujishima A,Honda K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238:37-38.
  • 2杨亚辉,陈启元,尹周澜,李洁.光催化分解水的研究进展[J].化学进展,2005,17(4):631-642. 被引量:15
  • 3傅宏刚,王建强,王哲,闫鹏飞,于海涛.TiO_2光催化剂表面修饰研究进展[J].黑龙江大学自然科学学报,2001,18(3):85-89. 被引量:15
  • 4张彭义,余刚,蒋展鹏.半导体光催化剂及其改性技术进展[J].环境科学进展,1997,5(3):1-10. 被引量:237
  • 5Zhibin Lei,Wansheng You,Can Li,et al.Photocatalytic Water reduction under visible light on a novel ZnIn2S4 catalyst synthesized by hydrothermal method[J].Chemical Communication,2003 (17):2142 -2143.
  • 6Shahed U M khan,Shahry M A,Ingler W B.Efficient Photochemical Water Splitting by a Chemical Modified n-TiO2[J].Science,2002,297:240-243.
  • 7Heyduk A F,Nocera D G.Hydrogen Production from Hydrohalic Acid Solutions by a Two-Electron Mixed-Valence Photocatalyst[J].Science,2001,293:1639-1641.
  • 8Asahi R,Morikawa T,Ohwaki T,et al.Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides[J].Science,2001,293:269-271.
  • 9Bessekhouad Y,Trari M,Doumere J P.CuMnO2,a novel hydrogen photoevolution catalyst[J].Int.J.Hydrogen Energy,2003,28:43-48.
  • 10Guo L J,Yan W.Photosplitting water under visible light with a series of composite photocatalysts[A].In:Proceedings of The International Hydrogen Energy Forum[C],Beijing.2004.

二级参考文献56

  • 1Fu X,Environ Sci Technol,1996年,30卷,2期,647页
  • 2Chen L C,Ind Eng Chem Res,1994年,33卷,6期,1436页
  • 3Liu D,Electroanal Chem Interfacial Eltronchem,1993年,347卷,451页
  • 4Wang C M,J Am Chem Soc,1992年,114卷,5230页
  • 5Gao Y M,Mater Res Bull,1991年,27卷,9期,1023页
  • 6Gao Y M,Mater Res Bull,1991年,26卷,12期,1247页
  • 7赵修建,超微颗粒导论(译),1991年,50页
  • 8黄敏明,金属氧化物及其催化作用(译),1991年,248页
  • 9梁娟,催化剂新材料,1990年,52页
  • 10果玉忱,半导体物理学,1988年,19页

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