摘要
A new mononuclear copper（Ⅱ） complex [（bipy）2Cu（PhCOO）]ClO4·（benzil） （bipy = 2,2＇-bipyridine, benzil = 1,2-diphenyl-ethane-1,2-dione） was synthesized by direct electrochemical oxidation of Cu electrode in an acetonitrile solution with benzoic acid, 2,2＇-bipyridine and benzoin. As soon as the current flowed in the cell, benzoin was oxidized to benzil quickly. The crystal structure was determined by X-ray diffraction. It belongs to monoclinic system, space group P21/c with a = 14.860（2）, b = 20.784（3）, c = 11.9150（17）A, β = 101.401（3）°, V= 3607.3（9）/k^3, Z = 4, M, = 806.69, D, = 1.485 g/cm^3, F（000） = 1660, μ = 0.742 mm^-1, R = 0.0788 and wR = 0.1519 for 6254 observed reflections （I 〉 2σ（I）. The complex contains a mononuclear [（bipy）2Cu（PhCOO）] cation, a solvate benzil molecule and a ClO4^- anion which locates around the cation outside acting as the counter ion. The Cu（ll） ion is coordinated by two 2,2＇-bipyridines and one benzoato ligand to form a distorted square-pyramid.
A new mononuclear copper（Ⅱ） complex [（bipy）2Cu（PhCOO）]ClO4·（benzil） （bipy = 2,2＇-bipyridine, benzil = 1,2-diphenyl-ethane-1,2-dione） was synthesized by direct electrochemical oxidation of Cu electrode in an acetonitrile solution with benzoic acid, 2,2＇-bipyridine and benzoin. As soon as the current flowed in the cell, benzoin was oxidized to benzil quickly. The crystal structure was determined by X-ray diffraction. It belongs to monoclinic system, space group P21/c with a = 14.860（2）, b = 20.784（3）, c = 11.9150（17）A, β = 101.401（3）°, V= 3607.3（9）/k^3, Z = 4, M, = 806.69, D, = 1.485 g/cm^3, F（000） = 1660, μ = 0.742 mm^-1, R = 0.0788 and wR = 0.1519 for 6254 observed reflections （I 〉 2σ（I）. The complex contains a mononuclear [（bipy）2Cu（PhCOO）] cation, a solvate benzil molecule and a ClO4^- anion which locates around the cation outside acting as the counter ion. The Cu（ll） ion is coordinated by two 2,2＇-bipyridines and one benzoato ligand to form a distorted square-pyramid.
基金
This work was supported by the National Natural Science Foundation of China (No. 20503019)
