一种含[Ni(CN)_4]^(2-)和[Cu(pn)]^(2+)构筑元组成的超分子配合物的合成、单晶结构和磁学性质(英文)
Synthesis, Crystal Structure and Magnetic Property of a Cyano-Bridged 3D Heterometallic Supramolecular Complex Containing [Ni(CN)_4]^(2-) and [Cu(pn)]^(2+) Tectons
摘要
A cyano-bridged heterometallic supramolecular complex {[Cu(pn)]3[Ni(CN)4]3}n (1) has been synthesized and structurally characterized by single crystal X-ray diffraction. 1 displays an interesting 3D structure formed by μ4, μ3-[Ni(CN)4]2- tectons bridging five-coordinated and six-coordinated Cu(Ⅱ) ions. The magnetic property shows that 1 behaves as weakly ferromagnetic interactions between the adjacent Cu(Ⅱ) ions through the diamagnetic spacer NC-Ni-CN. CCDC: 624387.
A cyano-bridged heterometallic supramolecular complex {[Cu（pn）]3[Ni（CN）4]3}n （1） has been synthesized and structurally characterized by single crystal X-ray diffraction. 1 displays an interesting 3D structure formed by μ4,μ3-[Ni（CN）4]^2- tectons bridging five-coordinated and six-coordinated Cu（Ⅱ） ions. The magnetic property shows that 1 behaves as weakly ferromagnetic interactions between the adjacent Cu（Ⅱ） ions through the diamagnetic spacer NC-Ni-CN. CCDC： 624387.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2007年第4期713-716,共4页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.206710214)
关键词
超分子配合物
单晶结构
磁性
supramolecular complex
single crystal structure
magnetic property
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