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重金属硫化矿物溶解度的近似计算及其讨论

Approximate Calculation on Solubility for Sulphide Minerals of Heavy Metal
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摘要 在H.C.Helgeson等人根据热力学导出的简单矿化物(MS型)溶解度公式的基础上,引进了ψ函数,考虑了氧化还原电位Eh对溶解度的影响,导出了新的硫化物溶解度公式。 Based on the formula of common minerals solubility educed according to thermodynamics by H. C. Helgeson, et al, the function Ψ is imported and the impacts of oxidation - reduction electric potential Eh are considered for solubility, which export a new formula of sulphide solubility.
作者 陈履安
出处 《贵州地质》 2006年第4期307-311,共5页 Guizhou Geology
关键词 重金属硫化物 矿物 溶解度 PH EH 近似计算 sulphide of heavy metal minerals solubility pH Eh approximate calculation
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参考文献8

  • 1Nriagu,J.O.,Expressions for Calculating the Solubility's of metal Sulfides in hydro-thermal Solutions,Can.Jour.Eartg Sa.,1971,Vol8,813 -319.
  • 2Helgeson,H.C.,Thermodynamics of hydrothermal Systems at elevated temperature and Pressures,Am,Jour,Sci 1969,Yol,267,729-804.
  • 3Cobble,I.W.,Empirical Consideration of enthopy Ⅱ,The enthopy of inorganic Complexes ions,J.Chem.Phys.,1953,Vol.21 No.9,1446.
  • 4Criss,C.M.,and J.W.Cobble,The thermodynamic Properties of High temperature aqueous Solutions,J.Am.Chem.Soc,1964,Vol.86,No.24,5390-5401.
  • 5Barnes,H.L.and G.K..Czamanske,Solubility and transport of ore minerals:Geochemistry of Hydrothermal Ore Deposits 1st ed.,by H..L.Barnes,ed.,New York,1967,334-381.
  • 6Anderson,G.M Thermodynamics and Sofubilities of sulfides:Application of Thermodynamics to petrology and Ore Deposits,by H.J.Greenwood,ed.,Mineralogical Association of Canada,.1977,135-145.
  • 7陈履安.从HgS-NaCI-HCl-H2O体系的热力学分析探讨辰砂以氯汞络合物运移成矿所需的物理化学条件.贵州地质,1985,2(3).
  • 8陈履安.HgS-C1-H2O体系中汞矿物的稳定场和其溶解类型的优势场的Eh-pH图及其地质意义.地质论评,1984,30(2).

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