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Synthesis of a new 2,2':6',2''-terpyridine derivative and its coordination property

Synthesis of a new 2,2':6',2''-terpyridine derivative and its coordination property
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摘要 A novel compound, (E)-4′-(4-(but-1-en-3-ynyl)phenyl)-2,2′:6′,2″-terpyridine 1 was synthesized from 4′-(4-bromomethylphenyl)-2,2P:6P,2PP-terpyridine phosphonium salt 2 and propargylaldehyde via Wittig reaction, and characterized by EI-MS and ^1H NMR as well as elemental analysis. The spectral changes of the compound in the presence of transition metal ions, such as Cu(I) or Zn(ID, are investigated. A novel compound, (E)-4′-(4-(but-1-en-3-ynyl)phenyl)-2,2′:6′,2″-terpyridine 1 was synthesized from 4′-(4-bromomethylphenyl)-2,2P:6P,2PP-terpyridine phosphonium salt 2 and propargylaldehyde via Wittig reaction, and characterized by EI-MS and ^1H NMR as well as elemental analysis. The spectral changes of the compound in the presence of transition metal ions, such as Cu(I) or Zn(ID, are investigated.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2007年第5期530-532,共3页 中国化学快报(英文版)
关键词 Polypyridine ligands SYNTHESIS COORDINATION Polypyridine ligands Synthesis Coordination
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