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巯基／乙烯基硅氮烷体系的紫外光聚合机理及动力学研究

Study on mechanism and kinetics of photopolymerization for thiol-vinyl silazane system
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摘要 乙烯基硅氮烷(VL20)是一种液态陶瓷前驱体,在光引发剂存在下与巯基化合物快速发生光聚合反应。文中利用先进的紫外光差示扫描量热(UV-DSC)实时跟踪和博里叶变换红外光谱(FTIR)原位跟踪等方法,研究了巯基-乙烯基硅氮烷VL20体系的光聚合反应机理和动力学特征。 The vinyl silazane （VL20） is a kind of !iquid ceramic precursor. The VL20 and thiol compounds can photopolymerize quickly under photoinitiator and form polymers. In this paper,the mechanism and kinetics of photopolymerization of thiol-VL20 have been studied by the means of advanced UV.DSC real-time monitoring and FTIR in-situ monitoring.
作者 陈伟伟 陈立新 宋家乐 王亚洲 张教强 王汝敏
机构地区 西北工业大学理学院应用化学系空间应用物理与化学教育部重点实验室
出处 《中国胶粘剂》 CAS 2007年第4期5-9,共5页 China Adhesives
基金 国家自然科学基金(No.20574056) 总装备部预研基金(No.9140A12070106HK0338) 西北工业大学博士论文创新基金(No.CX200614) 西北工业大学研究生创业种子基金(No.Z200663)资助项目。
关键词 巯基-乙烯基 光聚合 机理 动力学 博里叶变换红外光谱 紫外光差示扫描量热 thiol-ene photopolymerization mechanism kinetics FrlR UV-DSC
分类号 TQ034 [化学工程]
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参考文献11

  • 1陈榕珍,成荣明,李国庆,刘永登,陈奕卫,徐学诚.UV固化聚丙烯酸酯压敏胶的制备及其性能研究[J].中国胶粘剂,2006,15(8):28-30. 被引量：20
  • 2T M ROPER,T KWEE,T Y LEE,et al.Photopolymerization of pigmented thiol-ene systems[J].Polymer,2004,45 (9):2 921-2 929.
  • 3LI-ANNE LIEW,WENGE ZHANG,VICTOR M BRIGH,et al.Fabrication of SiCN ceramic MEMS using injectable polymer-precursor technique[J].Sensors and Actuators A:Physical,2001,89 (1-2):64-70.
  • 4CHIOU B S,ENGLISH R J,KHAN S A.Rheology and photo-crosslinking of thiol-ene polymers[J].Macromolecules,1996,29(16):5 368-5 374.
  • 5NEIL B CRAMER,CHRISTOPHER N BOWMAN.Kinetics of thiol-ene and thiol-acrylate photopolymerizations with real-time Fourier transform infrared[J].Journal of Polymer Science:Part A:Polymer Chemistry,2001,39 (19):3311 -3319.
  • 6CHARLES E HOYLE,TAI YEON LEE,TODD ROPER.Thiol-enes:chemistry of the past with promise for the future[J].Journal of Polymer Science:Part A:Polymer Chemistry,2004,42:5301-5338.
  • 7NEIL B CRAMER,SIRISH K REDDY,HUI LU,et al.Thiol-ene photopolymerization of polymer-derived ceramic precursor[J].Journal of Polymer Science:Part A:Polymer Chemistry,2004,42:1 752-1 757.
  • 8袁慧雅,王志明,曾兆华,杨建文,陈用烈.聚氨酯丙烯酸酯光固化反应动力学的研究[J].热固性树脂,2001,16(3):5-8. 被引量：19
  • 9L LECAMP,B YOUSSEF,C BUNEL.Photoinitiated polymerization of a dimethacrylate oligomer:1.Influence of photoinitiator concentration,temperature and light intensity[J].Polymer,1997,38 (25):6 089-6 096.
  • 10E W NELSON,J L JACOBS,A B SCRANTON.Photodifferential scanning calorimetry studies of cationic polymerizations of divinyl ethers[J].Polymer,1995,36 (24):4 651-4 656.

二级参考文献16

  • 1陈用烈,郑牧,梁兆熙.光引发阳离子聚合反应的研究Ⅲ．硫鎓盐BDS引发环氧化合物光聚合的DSC研究[J].应用化学,1994,11(2):27-30. 被引量：12
  • 2Hu H F Xu M J 等.A Study on Kinetics of Acrylic System in UV Curing[J].上海大学学报（自然版）,1996,2(5):502-502.
  • 3Morgan C R, Magnotta F, KetleyA D.Thiol/ene photocurable polymers [J].Journal of Polymer Science: Polymer Chemistry Edition,1977,15(3):627-645.
  • 4Yong Liechen, Bengt Ranby.Photocrosslinking of polyethylene.I.Photoinitiators,crosslinking Agent,and reaction kinetics [J].Journal of Polym Science, Part A: Polym Chem,1989,27(12):4 051-4 075.
  • 5Bor-Sen C,English R J,SaadA K.RheologyAnd photo-cross-linking of thiol-ene polymers [J].Macromolecules,1996,29(16):5 368-5 374.
  • 6Bor-Sen C,SaadA K.Real-time FTIRAnd in situ rheological studies on the UV curing kinetics of thiol-ene polymers[J].Macromolecules,1997,30(23):7 322-7 328.
  • 7Eisele G, Fouassier J P, Reeb R.Kinetics of photocrosslinking reactions ofA DCPA/EA matrix in the presence of thiols And Acrylates[J].Journal of Polymer Science, PartA: Polymer Chemistry,1997,35(12):2 333-2 345.
  • 8Decker C,Nguyen T, Viet T.Photocrosslinking of functionalized rubbers IX.Thiol-ene polymerization of styrene-butadiene-block-copolymers [J].Polymer, 2000,41(11):3 905-3 912.
  • 9Decker C,Nguyen T,Viet T.Photocrosslinking of functionalized rubbers.X.Butadiene-acrylonitrile copolymers[J].Journal of Applied Polymer Science,2001,82(9):2 204-2 215.
  • 10Cramer N B, Bowman C N.Kinetics of thiol-ene And thiol-acrylate photopolymerization with real-time Fourier transform infrared[J].Journal of Polymer Science, PartA: Polymer Chemistry,2001,39(19):3 311-3 319.

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中国胶粘剂
2007年 第4期

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