硼酸漆酚酯聚合物的合成、表征及其特性研究

A Study on Synthesis, Characterization and Property of Polymer of Urushiol Borate

通过漆酚与硼酸正丁酯的酯交换反应和溱酚的不饱和直碳链基在空气中氧的作用下的聚合反应制得硼酸漆酚酯聚合物．用红外光谱、荧光光谱、高效液相色谱、核磁共振硼谱和热分析等对硼酸漆酚酯聚合物进行表征，并研究了该聚合物的配合性．

Polymer of di-urushiol borate (PDUB) was synthesized by the ester exchange reaction of urushiol with tri-n-butyl borate and okidation polyrnerization of double bonds contained in the alkenyl side-chain of urushiol in the air. The PDUB was characterized by IR,llKNMR, TG, HPLC and fluorescence spectrum. The coordinate prop-erty of PDUB was reported.