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桥连或取代环戊二烯基(茚基)钌-钌键羰基化合物的研究进展 被引量：1

Progress in Bridged or Substituted Cyclopentadienyl(and Indenyl) Ru-Ru Bond Carbonyl Complexes
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摘要 综述了桥连或取代环戊二烯基(茚基)钌-钌键羰基化合物的研究进展,讨论了它们的合成、结构及其反应性.对于非桥连配合物而言,影响化合物分子结构和金属-金属键反应活性的因素,则是茂环上取代基的立体效应和电子效应;而对于桥连配合物来说,除了茂环上取代基的立体效应和电子效应外,桥连配体化合物中的桥是影响化合物结构和反应活性的一个至关重要的因素. The progresses in bridged or substituted cyclopentadienyl（and indenyl） Ru-Ru Bond carbonyl complexes are summarized. Their synthesis, molecular structure and reactivity are discussed. For non-bridged complexes,the steric and electronic effects of the substituent in the cyclopentadienyl ring are factors that influence complex structure and reactivity of M-M bond. But for bridged complexes, the bridges except the substituent in the cyclopentadienyl ring are very important factors.
作者 林进
机构地区 河北师范大学化学与材料科学学院
出处 《河北师范大学学报（自然科学版）》 CAS 北大核心 2007年第3期369-374,共6页 Journal of Hebei Normal University：Natural Science
基金 河北师范大学博士基金(L2005B18)
关键词 环戊二烯基 茚基 钌-钌键 羰基化合物 cyclooentadienyl indenyl Ru- Ru bond carbonyl complexes
分类号 O627.8 [理学—有机化学]
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参考文献30

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同被引文献31

  • 1林进.桥连或取代环戊二烯基(茚基)铁—铁键羰基化合物的研究进展[J].有机化学,2007,27(10):1228-1235. 被引量：1
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  • 3WITTE P,LAL T K,WAYMOUTH R M.Synthesis of Unbridged Bis(2-R-indenyl)Zirconocenes Containing Functional Groups and Investigations in Propylene Polymerization[J].Organometallics,1999,18(20):4147-4155.doi:10.1021/om990083w.
  • 4MUTSENECK E V,PETROVSKII P V,KUDINOV A R.Synthesis of Slippedμ-indenyl Triple-decker Complexes Containing(C4Me4)Co and(C5Me5)Ru Fragments[J].Russ Chem Bull,2004,53(9):2090-2091.doi:10.1007/s11172-005-0078-x.
  • 5TRIFONOV A A,FEDOROVA E A.Bridgingμ-η5:η4-coordination of an Indenyl Ligand and Reductive Coupling of Diazabutadienes in the Assembly of Di-and Tetranuclear Mixed-valent Ytterbium Indenyldiazabutadiene Complexes[J].Chem Eur J,2006,12(10):2752-2757.doi:10.1002/chem.200501181.
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  • 8BRUCE M I,SKELTON B W,WHITE A H,et al.Cyclisation of Allenylidene Ligands to Indenyl Groups on Ruthenium Clusters[J].J Cluster Sci,2002,13(2):235-247.doi:10.1023/A1015552103043.
  • 9CHEN D F,MU B,XU S S,et al.Synthesis and Structures of the Silyl Bridged Bis(indenyl)Diruthenium Complexes and a Novel Indenyl Nonanuclear Ruthenium Cluster Ru9(μ6-C)(CO)14(μ3-η5:η2:η2-C9H7)2[J].J Organomet Chem,2006,691(18):3823-3833.doi:10.1016/j.jorganchem.2006.05.030.
  • 10TAN Y L K,LEONG W K.Reactivity of the Heteronuclear Cluster RuOs3(μ-H)2(CO)13with Indene[J].J Organomet Chem,2007,692(4):768-773.doi:10.1016/j.jorganchem.2006.10.010.

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河北师范大学学报（自然科学版）
2007年 第3期

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