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Effects of sodium tungstate on characteristics of microarc oxidation coatings formed on magnesium alloy in silicate-KOH electrolyte 被引量:10

Effects of sodium tungstate on characteristics of microarc oxidation coatings formed on magnesium alloy in silicate-KOH electrolyte
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摘要 Oxide coatings on AM60B magnesium alloy were prepared using the microarc oxidation(MAO) technique in silicate-KOH electrolyte with addition of 0-6.0 g/L Na2WO4. The MAO processes in base electrolyte with different concentrations of Na2WO4 were studied. The microstructure, compositions and mechanical tribological characteristics of the oxide coatings were also investigated by SEM, XRD, XPS, microhardness analysis and ball-on-disc friction testing, respectively. It is found that the addition of Na2WO4 into the base electrolyte has direct effect on the characteristics of voltage—time curves and breakdown voltage in MAO process. The number of micropores at top of the coating surface is increased by the addition of Na2WO4. The fraction of forsterite Mg2SiO4 in the oxide coating increases with increasing concentration of Na2WO4 in base electrolytes. Furthermore, the microhardness and wear resistance of oxide coatings are enhanced as well. Oxide coatings on AM60B magnesium alloy were prepared using the microarc oxidation(MAO) technique in silicate-KOH electrolyte with addition of 0-6.0 g/L Na2WO4. The MAO processes in base electrolyte with different concentrations of Na2WO4 were studied. The microstructure, compositions and mechanical tribological characteristics of the oxide coatings were also investigated by SEM, XRD, XPS, microhardness analysis and ball-on-disc friction testing, respectively. It is found that the addition of Na2WO4 into the base electrolyte has direct effect on the characteristics of voltage-time curves and breakdown voltage in MAO process. The number of micropores at top of the coating surface is increased by the addition of Na2WO4. The fraction of forsterite Mg2SiO4 in the oxide coating increases with increasing concentration of Na2WO4 in base electrolytes. Furthermore, the microhardness and wear resistance of oxide coatings are enhanced as well.
出处 《中国有色金属学会会刊:英文版》 EI CSCD 2007年第2期244-249,共6页 Transactions of Nonferrous Metals Society of China
基金 Projects(50432020, 50575218) supported by the National Natural Sicence Foundation of China
关键词 钨酸钠 微弧氧化涂层 镁合金 硅酸盐-氢氧化钾电极 magnesium alloy microarc oxidation Na2WO4 oxide coating wear resistance
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