摘要
研究了锕系元素Am3+和镧系元素Eu3+、Nd3+在D301-DHDECMP树脂上的交换容量、吸附速率及溶液酸度对分配比的影响,并对D301-DHDECMP树脂吸附Eu、Nd前后的红外光谱图作了分析和比较。实验表明:D301-DHDECMP树脂和DHDECMP萃取剂在HNO3介质中均对锕系和镧系元素具有较强的吸附能力。分配比随着溶液中硝酸浓度的增加而增加,在HNO3浓度大于8mol/L时,分配比有所回落;到10mol/L时,再随酸度升高而上升。D301-DHDECMP树脂对Am3+、Eu3+、Nd3+具有很好的吸附动力学性能,在1min内即可达到吸附平衡。在酸性介质内对Eu、Nd的交换容量分别为0.28、0.
Batch experiments show that the D301-DHDECMP resin has a high exchange capacity for Nd 3+ and Eu 3+ and the exchange epuilibrium can be obtained in one minute.The relationship between the distribution coefficient and solution acidity is similar to that of DHDECMP.Infrared spectra and kinetic study show that the bonding sites of the resin are mainly phosphoryl.
出处
《核技术》
CAS
CSCD
北大核心
1997年第1期34-38,共5页
Nuclear Techniques
关键词
树脂
锕系元素
镧系元素
吸附
DHDECMP,Chelating resin,Lanthanide,Actinide