摘要
本文通过重氮化反应设计、合成了鲁米诺偶联的氨基锌酞菁,对其电子吸收光谱和荧光光谱性质进行了研究,结果表明该分子激发单重态可能以振动驰豫的方式使大部分能量耗散,鲁米诺偶联前后,氨基取代锌酞菁的荧光光谱有明显差别,为进一步开发酞菁类荧光光存储材料提供了理论依据.
α-Tetra-amino-phthalocyanine zinc（ Ⅱ ） conjugating luminols was designed and synthesized by diazotization method. The electronic absorption spectra and fluorescence spectra of the compound in DMF have been measured and studied. The phenomena of intramolecular electron transfer are found and the fluorescence of phthalocyanine was quenched significantly by luminol moiety. These results showed potential applications in fluorescence data storage.
出处
《感光科学与光化学》
EI
CSCD
2007年第3期209-213,共5页
Photographic Science and Photochemistry
基金
国家自然科学基金项目(20333080
20572059
20502013)
国家基础研究项目(2007CB808000)
关键词
鲁米诺
氨基取代锌酞菁
电子转移
荧光存储
luminol
amino substituted phthalocyanine zinc（ Ⅱ）
electron transfer
fluorescence data storage
