摘要
提出了配合物稳定常数的一种新计算方法。在计算中考虑了配合物的离子性、共价性、酸碱的软硬性及空间效应。该法能用于软酸、软碱及螯合物体系,并得到了满意的结果。
A new method has been used for calculation stability constants of metal com-plexes. The ionic property, covalent property, softness of acid or base and stericeffect are quantitatively related to the stability constants of metal complexes. Themethod can be used in soft acid or soft base system and chelate compound systemwith satisfactory result.
出处
《复旦学报(自然科学版)》
CAS
CSCD
北大核心
1990年第1期64-70,共7页
Journal of Fudan University:Natural Science
关键词
配合物
稳定常数
多参数法
coordination compounds, stability constants, calculation
multiparatneter method.