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Na_2S溶液吸收低浓度SO_2的动力学研究 被引量:3

Kinetics study on absorption of sulfur dioxide from dilute gases in sodium sulfide aqueous solution
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摘要 This paper concerns about the macrosopic kinetics of absorption of sulfur dioxide from dilute gases by sodium sulfide aqueous solution.It has been shown that there are three stages in the process in accordance to the profile of pH value change.Sulfur dioxide has been fully absorbed in stage I and stage II;stage III is continuously capable of absorption of sulfur dioxide,but the stage is signed by sulfur dioxide detected in the exit gas flows.In addition,the gas film mass transfer controlling ste Pis observed for the absorption of sulfur dioxide in stage I and stage II.The temperature of sodium sulfide aqueous solution negatively influences the overall rate of absorption of sulfur dioxide and the concerntration of sodium sulfide aqueous solution does not influence the overall rate. This paper concerns about the macrosopic kinetics of absorption of sulfur dioxide from dilute gases by sodium sulfide aqueous solution. It has been shown that there are three stages in the process in accordance to the profile of pH value change. Sulfur dioxide has been fully absorbed in stage Ⅰ and stage Ⅱ; stage Ⅲ is continuously capable of absorption of sulfur dioxide, but the stage is signed by sulfur dioxide detected in the exit gas flows. In addition, the gas film mass transfer controlling ste Pis observed for the absorption of sulfur dioxide in stage I and stage II. The temperature of sodium sulfide aqueous solution negatively influences the overall rate of absorption of sulfur dioxide and the concemtration of sodium sulfide aqueous solution does not influence the overall rate.
出处 《化学研究与应用》 CAS CSCD 北大核心 2007年第5期517-520,共4页 Chemical Research and Application
基金 武汉市科委重点攻关计划项目(996002062G)资助
关键词 硫化钠 低浓度二氧化硫 动力学 sodium sulfur sulfur dioxide from dilute gas kinetics
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