摘要
论述了六元环碳酸酯三亚甲基环碳酸酯(TMC)或2,2-二甲基三亚甲基环碳酸酯(DTC)与己内酯(ε-CL)开环共聚合的研究进展,概括了每种催化剂催化DTC或TMC与ε-CL开环共聚合的特征,并讨论了稀土催化剂在生物降解聚合物合成中的优势。
The copolymerizations of trimethylene carbonate （TMC） or 2,2-dimethyltrimethylene carbonate （DTC） with ε-caprolactone （ε-CL） were reviewed. The characteristics of the copolymerizations catalyzed by each kind of catalyst were generalized, and the advantages of rare earth catalysts for the synthesis of biodegradable polymers were discussed.
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
2007年第3期6-10,共5页
Polymer Materials Science & Engineering
基金
国家自然科学基金资助项目(20254001)
关键词
环碳酸酯
己内酯
开环共聚合
稀土催化剂
cyclic carbonate
ε-caprolactone
ring-opening copolymerization
rare earth catalyst
