超分子配合物{[Cd(phen)_3]·NDC·8(H_2O)}的合成、晶体结构和性质

Synthesis,Crystal Structure and Properties of Supramolecular Complex Based on PHEN and Naphthalene-2,6-dicarboxylic Acid Ligands

利用水热合成反应制备了超分子配合物{[Cd(phen)3].NDC.8(H2O)}(1)(phen邻菲啰啉;H2NDC2,6-萘二酸),通过元素分析和单晶X射线衍射对配合物表征.单晶X射线衍射分析表明,配合物1属于三斜晶系,P1空间群,a=1.2010(2)nm,b=1.2864(3)nm,c=1.7097(3)nm,α=74.21(3)°,β=69.92(3)°,γ=71.40(3)°,V=2.3117(8)nm3,Z=2,R1=0.0660,wR2=0.2043.荧光光谱分析结果表明,配合物1在紫外光的激发下有光致发光特性.

A supramolecular complex { [ Cd （phen） 3 ] · NDC · 8 （ H2 O）}（ 1 ） （ phen ： 1,10-phenanthroline, NDC： 2,6-naphthalenedicarboxylate） was synthesized under hydrothermal condition and characterized with elemental analysis and single-crystal X-ray diffraction. Complex 1 crystallized in the triclinie system with space group P1^-, a = 1.201 0（2） nm, b = 1.286 4（3） nm, c = 1.709 7（3） nm, α= 74. 21 （3）°, β = 69. 92 （3）°, γ=71.40（3）°, V=2.311 7（8） nm^3, Z=2, R1 =0.0660, wR2 =0.204 3. This complex shows photoluminescence property, indicating that it may be applied in the development of luminescent materials.