配位键理论的形成与发展

Coordination Key to the Formation and Development of Theory

配位化合物的形成与发展经历了三个重要的时期,首先是维尔纳配位理论的形成;其次是鲍林等创立了配位价键理论;第三是现代晶体场—配位体场理论的建立。对其发展的演化进行分析研究,有助于深入认识和理解它的现状,并从中获得有益的启示,作为配位化学教学与科研的借鉴。

The discoveries and developments of coordination compounds have gone through three different periods： firstly, the building of coordination theory proposed by Werner, secondly, the foundation the valence- bonded theory presented by Pauling et al, and thirdly the establishment of modern theory of crystal field and coordination field. Analysis and research on the development and evolvement of coordination compounds are helpful to understand the present case of coordination compounds and achieve some inspirations for the teaching and scientific research on coordination chemistry.