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丝网印刷纳晶多孔TiO_2薄膜电极的制备 被引量：6

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摘要 应用丝网印刷技术制备TiO2多孔薄膜电极,采用了不同的印刷胶体,胶体中的主要成分TiO2来自商品P25粉末,各种胶体组成简单,电极制备前后不需任何化学处理,在TiO2固含量及膜厚较低的情况下,电池的光电转换效率可达5.81%～6.70%,实验的重复性好,所制薄膜的性质均匀、牢固.
作者 解东梅 冯树京 林原 董国君 肖绪瑞 李学萍 周晓文
机构地区 北京分子科学国家实验室中国科学院光化学重点实验室 哈尔滨工程大学材料科学与化学工程学院
出处 《科学通报》 EI CAS CSCD 北大核心 2007年第9期1007-1011,共5页 Chinese Science Bulletin
基金 国家自然科学基金(批准号:20373075和50221201)资助项目
关键词 丝网印刷 胶体 TIO2薄膜 染料敏化太阳能电池
分类号 O484.1 [理学—固体物理]
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参考文献9

  • 1Murakoshi K, Kano G, Wada Y, et al. Importance of binding states between photosensitizing molecules and the TiO2 surface for efficiency in a dye-sensitized solar cell. J Electroanal Chem, 1995, 396(1): 27--34
  • 2Nazeeruddin M K, Kay A, Rodicio I, et al. Conversion of light to electricity by cis-X2bis(2,2'-bipyridyl-4,4'-dicarboxylate) ruthenium(Ⅱ) charge-transfer sensitizers (X = Cl^-, Br^-, I^-, CN^-, and SCN^-) on nanocrystalline TiO2 electrodes. J Am Chem Soc, 1993, 115(14): 6382--6390
  • 3Argazzi R, Bignozzi C A, Heimer A T, et al. Enhanced spectral sensitivity from ruthenium(Ⅱ) polypyridyl based photovoltaic devices. Inorg Chem, 1994, 33(25): 5741--5749
  • 4马玉涛,林原,肖绪瑞,李学萍,周晓文.TiO_(2)纳米管薄膜的制备及其光散射性能[J].科学通报,2005,50(17):1824-1828. 被引量：14
  • 5Nazeeruddin M K, Pechy P, Renouard T, et al. Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2-based solar cells. J Am Chem Soc, 2001, 123(8): 1613--1624
  • 6Jing K J, Kitamura T, Yin H, et al. Dye-sensitized solar cells using brookite nanoparticle TiO2 films as electrodes. Chem Lett, 2002, 9: 872--873
  • 7Ma T, Kida T, Akiyama M, et al. Preparation and properties of nanostructured TiO2 electrode by a polymer organic-medium screen-printing technique. Electrochem Comm, 2003, 5(4): 369-- 372
  • 8Wang Z S, Yanagida M, Sayama K, et al. Electronic-insulating coating of CaCO3 on TiO2 electrode in dye-sensitized solar cells: Improvement of electron lifetime and efficiency. Chem Mater, 2006, 18(12): 2912--2916
  • 9Wang Z S, Yamaguchi T, Sugihara H, et al. Significant efficiency improvement of the black dye-sensitized solar cell through protonation of TiO2 films. Langmuir, 2005, 21:4272--4276

二级参考文献20

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  • 7Wang Z S, Kawauchi H, Kashima T, et al. Significant influence of TiO2 photoelectrode morphology on the energy conversion efficiency of N719 dye-sensitized solar cell. Coordination Chemistry Reviews, 2004, 248: 1381～1389.
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科学通报
2007年 第9期

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