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从配位聚合物到单分子化合物的转化:Demko-Sharpless四唑合成法制备两个新颖的Co(Ⅱ)配合物(英文) 被引量：1

From Coordination Polymer to Monomeric Complex:Two Cobalt Complexes from a Single Demko-Sharpless's Tetrazole Synthesis Reaction
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摘要 The reaction of CoCl2·6H2O with 4-cyanopyridine N-oxide in the present of NaN3 affords two novel complexes, {[(POTZ)(H2O)2N3]Co(H2O)} (1) and Co(POTZ)2(H2O)4 (2) (POTZ=4-tetrazolyl pyridine N-oxide), which are two different phases yielded at different stages of a single Demko-Sharpless' tetrazole synthesis reaction. Surprisingly the 1D chain coordination polymer 1 is almost completely converted into monomeric complex 2 in this reaction, and, in a separate test, 2 also can be converted into 1. CCDC: 641222, 1; 641223, 2. The reaction of CoCl2·6H2O with 4-cyanopyridine N-oxide in the present of NaN3 affords two novel complexes, {[（POTZ）（H2O）2N3]Co（H2O）} （1） and Co（POTZ）2（H2O）4 （2） （POTZ=4-tetrazolyl pyridine N-oxide）, which are two different phases yielded at different stages of a single Demko-Sharpless＇ tetrazole synthesis reaction. Surprisingly the 1D chain coordination polymer 1 is almost completely converted into monomeric complex 2 in this reaction, and, in a separate test, 2 also can be converted into 1. CCDC： 641222, 1; 641223, 2.
作者 瞿志荣
机构地区 东南大学化学化工学院
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2007年第6期1117-1120,共4页 Chinese Journal of Inorganic Chemistry
基金 东南大学启动基金资助项目。
关键词 配位聚合物 四唑 晶体结构 coordination polymer tetrazole crystal structure
分类号 O614.82 [理学—无机化学]
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参考文献16

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二级参考文献135

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无机化学学报
2007年 第6期

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