摘要
对淀粉接枝丙烯酸所得接枝共聚物及接枝侧链物进行分离提纯和分析测试,确定了其接枝效率并表征了淀粉及其接枝物的形态结构;通过分别测定接枝共聚反应速率与淀粉、单体、引发剂浓度的关系曲线,确定了该接枝共聚反应的速率关系式;推算出了反应的表观活化能。
This article confirmed the grafting efficiency of starch grafted to acrylic acid and the structure of starch and its grafted matter through the separation, purification and analysis tests to the grafted copolymer and the grafted forked-chain matter produced from the process of this reaction; and deduced the formula of the velocity of such reaction mentioned above with a calculated result of the apparent activation energy in this reaction by the curve showing the relationship among the consistency of starch, monomer and initiator and the velocity of the grafting copolymerization.
出处
《实验室研究与探索》
CAS
2007年第6期26-29,共4页
Research and Exploration In Laboratory
关键词
引发剂
丙烯酸
接枝共聚
反应动力学
initiator
acrylic acid
grafting copolymerization
reaction kinetics
