稀土金属有机羧酸骨架材料Tb(BTC)(DMF)(DMSO)的单晶结构与性能分析

Preparation and property analysis of Tb(BTC)(DMF)(DMSO)/rare earth metal organic carboxylate frameworks

选择稀土金属Tb作为功能性的金属中心与有机配体均苯三甲酸构筑了一种新型稀土金属有机羧酸骨架材料Tb(BTC)(DMF)(DMSO).通过对化合物Tb(BTC)(DMF)(DMSO)的单晶结构与荧光性、热稳定性和吸附性分析,表明该化合物在催化、吸附和荧光材料领域有潜在的应用前景.

Metal-organic coordination framework materials have attracted much attention in recent years due to their inherent design flexibility and highly-porous scaffolds, which make them potentially useful in a number of applications such as gas storage, optics, magnetics, catalysis etc. Here, we selected organic ligand BTC coordinated to rare-earth metal Tb to construct a novel rare-earth metal-organic carboxylate framework Tb(BTC)(DMF)(DMSO). This compound could be potentially used for catalysis, adsorption and fluorescence according to the characterization of relative properties.