Fischer-Tropsch Reaction Kinetics of Cobalt Catalyst in Supercritical Phase

在超级批评阶段状况下面的 Fischer-Tropsch 被检验在一连续并且由采用钴催化剂的一个高压的固定床反应堆(Co-Ru/|?-Al2O3) 。在超级批评液体 n 己包含 Fischer-Tropsch 动力学的一个积分反应器模型被用来描述全面表演。根据 Langmuir-Hinshelwood-Hougen-Watson (LHHW ) 模型，反应速率常数在超级临界情况下面为公司变换的速率公式被获得到 CH4 形成。给词调音：Fischer-Tropsch；超级批评阶段；n 己；动力学；

Fischer-Tropsch synthesis under supercritical phase condition was examined in a continuous and a high-pressure fixed bed reactor by employing a cobalt catalyst （Co-Ru/γ-Al2O3）. An integral reactor model involving Fischer-Tropsch reaction kinetics in the supercritical fluid n-hexane was used to describe the overall performance. On the basis of Langmuir-Hinshelwood-Hougen-Watson （LHHW） model, the reaction rate constants were obtained for the rate equations of CO conversion to CH4 formation under supercritical conditions.