摘要
异构的 Cu-Mn 混合了氧化物能调停由在中立状况下面的分子的氧的本甲基酒精的催化速度的选择氧化,并且是 recyclable。在超过 1 的 Cu 和 Mn 的摩尔比率的情况中,在 Cu-Mn 内的高度分散的 CuO 混合了氧化物为在催化氧化的好表演负责。给词调音:Cu-Mn 氧化物;2,2,6,6-tetramethyl-piperidyl-l-oxyl;氧气的氧化;
Heterogeneous Cu-Mn mixed oxides can mediate TEMPO-catalyzed selective oxidation of benzyl alcohol by molecular oxygen under neutral condition, and is recyclable. In the case of the molar ratio of Cu and Mn over 1, the highly-dispersed CuO inside the Cu-Mn mixed oxides is responsible for the good performances in catalytic oxidation.
基金
the National Natural Science Foundation of China (No.20572102)
关键词
苯甲醇
催化作用
氧化物
需氧反应
Cu-Mn oxides
2,2,6,6-tetramethyl-piperidyl-l-oxyl
aerobic oxidation
benzyl alcohol